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1 Compounds with Transition Metal–Carbon π-Bonds and Compounds of Groups 10 - 8 (Ni, Pd, Pt, Co, Rh, Ir, Fe, Ru, Os)

DOI: 10.1055/sos-SD-001-00001

Lautens, M.Science of Synthesis, (200111.

This volume of Science of Synthesis describes compounds with transition-metalcarbon π-bonds for groups 108. It is the first volume in the category Organometallics and the first volume of the Science of Synthesis series. The elements covered are nickel, palladium, platinum, cobalt, rhodium, iridium, iron, ruthenium, and osmium.

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Mee eeeee eeeeeeee ee eeeeeeeeeeeeeee eeeeeee eeeee eeeeeeeee eeeee eee π-eeeeee eeeee eeeeeee ee eeeee eeeeeeee eee ee eeee eeeeeee eeeee ee eeeeeeeeeee eeeeeee eeeee eeeee π-eeeeeeeee eee eeeee eeeeeeeee ee e eeeee ee eeeeeeeee. Mee eeeeeeee ee eeeeeeeee eeeeeeeee eeee eeee eeee eeeeeeee eeeee ee eeeeeee eeeeeeeee ee eeeeeeeee eeee ee eeeeeee eeeeeee eeeeeee eee eeeeeeee ee e eeeee. Meee eeee eee eeee ee π-eeeeeee ee eeeeeeeee eeeeee eeeeee e eeeee, eee eee eeeeeeee ee eeeeeeeeee eeeee ee eee π-eeeeeee ee eeeeeee eeeeeeee eeee ee eeeeeeee (η8>η8>η8).

Me eeeeeee ee eeeeeeeeee eee eeeee ee eee eeeeeeeee-eeeeeeeee eeeeeeeeeeeeeeeee ee eeeeeee eeeeeeee eee eeeeeeeeeeee (Meeeee 8). Mee eeee eeeeee eeeeeeeee eeeeeeee eeeeeeeeeeee ee eee eeeeee eeee eeeeeeeee (η8-eeeeeee) eeeeeeee ee eeeeeeeeee ee eeee e π-eeeee eeeeeeeee eeeeeee (η8-eeeeeee). Meeeeeeeee eeeeeeee eeee e eeeeeeeeeee ee eeee e π-eeeeee eeeeeeeee eeeeeee (η8-eeeeeee) eeeeee. Mee eeeeeee ee eeeeeee eeeeeeee ee eeee eeeee ee eee η8-eeeee eeeeeee eee ee eeeeeeeee ee eeee eeee eee eeeee ee Meeeeee 8.8.8 (MeeeeeeeeMeeee Meeeeeeee).

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Me eee eeeeeeeee eeeeeee, eeeeeeee eeeeeeee eeeeeeeeee eeee eee eeeeeeeeee eeeeeeee eee eeeeeeeee ee eeeee ee eeeeeeeee eee eeeeeeeee ee eeeeeeeee eeeeeeeee ee π-eeeeeeeee eeeeeee ee eeee eeeeee.

Meeeeee 8.8.8 eeeeee eee eeeeeee eeeee ee eeeeeeeeeee eeeeeeeee eee ee Meeeeee 8.8.8.8.8 e eeeeeeeeeee eeeeeee ee eeeeeeee ee ee eeeeeeee ee e eeeeeeeee-eeeeeeee eeeeeee eeeeeeee ee eeeeee(8). (8M,8M)-Meee-8,8-eeeeeeee eeeeee eeee ee eeeeeeee ee eee eeeeeeee ee eeeeeeeeeeeeee ee eeee eee eeeeeee eeeee ee 88% eeeee (Meeeee 8).[‌8‌]

Meeeee 8 Meeeeeeee Meeeeeee eeee Meeeeeeeeeeeee[‌8‌]

Me eeeeeeeee eeeee, Meeeeee 8.8 eeeeee eee π-eeeeeeeee ee eeeeeeeee. Meeeeee 8.8.8.8.8 eeeeeeee eee eeeeeeeee eee eeeeeeeee ee eeeeee π-eeeeeeeee eeeeeeeee eee ee eee eeee eeeeeeeee eeeeeeeee eeeeeeeeeeeeeee, eee Meeeee eeeeeeeee. M eeeeeeee eeeeeee ee eeeeeeeee eee eeeeeeeeeeeeeeee eee eeeeeeeee eeeeeee ee eeeee eeeee (Meeeee 8).[‌8‌]

Meeeee 8 Mee Meeeeeeeeeeeee Meeeeeeee-Meeeeeeee Meeeeeeee ee ee Meeeeeeee-Meeeeeeeeee 8-Meeeeeeeeeeeeeeeee ee e 8,8-Meeeeeeeee Meeeeeee[‌8‌,‌88‌]

Meeeeee 8.8.8 ee eeeeeee ee eee eeeeeeeee ee eeeeee eeeeeeeee ee eeeeeeee ee eeee ee eeeeeeeee eeeeeeeee eeeee e eeeeeeeeeeeeee eeeeeee ee e eeeeee eeeeeeeeeeee. Me Meeeeee 8.8.8.8.8, e eeeeeeeeeeeee eeeeeee ee eeeeeeeee eeeee e eeeeeeee eeeeee eeeeee eeee ee eeeeeeeeee eee eeeeee eeeeeeee ee eee eeeeeeee ee eeeeeeee(eeeeeeeeeeeeeeeeee)eeeeeeee(8) ee eeeee eee eeeeeee eeeeeee eeee eeeeeeee ee eee eeeeeeee eeeeeeee ee eee eeeeee (Meeeee 8).[‌8‌]

Meeeee 8 Meeeeeee-Meeeeeeee Meeeeeeeeeeee Meeeeeeeee ee ee Meeeee[‌8‌]

Meeeee π-eeeeeeeee eee eeeeeeeee ee eeee eeeeeeeeeeeeee eee eeeeeeeee eeeeeeeee. Me Meeeeee 8.8.8.8.8, e eeeeeeee eeeeeee e eeeeeeee eeeeeeeeeee eeeeeee eee e eee(eeeee) eeee eeeee ee eeeeeeee eeeee eeeeeeee eeeeee ee eeeee eeee eeeeeee ee eeee ee eeeeeeeee eeeee (Meeeee 8).[‌8‌]

Meeeee 8 Meeeeeee ee Mee(eeeeeeeeeeeeeee)eeeeee ee Meeeeeeeeee(η8-eeeee)eeeeee(M) Meeeeeeeeeeeeeeee Meeeeeeee[‌8‌]

Meeeeee π-eeeeeeeee (Meeeeee 8.8) eee eeeeee eeee ee eeeeeeeee eee eeeeeeeeee eee eeeeeeeeee-eeeee eeeeeeeee ee eeee eeeeeeeee eeeee. Meeee eee eeee eeeeee eee eeeee eeeeeeeee eeeee eeeeeeeeeeeee ee eeeeeeeee-8,8-eeeee eee eee eeeeeee. Meeeeee 8.8.8.8 eeeeeeee eee eeee eeeeee eeeeeeee ee eeeeee eeeee eeeeeeeee ee eeeeeee eeeee eee eeee eeee ee eeeeeeeee eeeeeee eee eeeeeeeeeeeee, eeeeeeeeeeeeee, eeeeeeeeeeeee, eee eeeeeeeeeeeee eeeeeeeee (Meeeee 8).[‌8‌,‌88‌]

Meeeee 8 Meeeeeeee ee Meeeeeee Meeeee Meeee Meeeeeeee[‌8‌,‌88‌]

Meeeeeeeeeee eeeeeeeee eee eeeeeeee eeeeeeeeeeee eeeeeeeee eeeeeee ee e eeeeeee ee eeeeeeeee eeeeeeeee. Mee eeee eeeeeeee ee eee eeeeeee-eee eeeeeee eeeee ee eeeee eee eeeeeeeee, eeeeee, eee, eeee eeeeeeee, eeeeeee, (Meeeeee 8.8.8.8 eee Meeeee 8).[‌88‌]

Meeeee 8 Meeeeee-Mee Meeeeeeeeee[‌88‌]

Meeeeee π-eeeeeeeee (Meeeeee 8.8) eee eeeeeeee eeeeeee ee eeeeeeeeeeee ee eeeeeee eeeeeeeee eee eee eeeeeeeeee eeeeeeee ee eeeeeeeeeeeee ee eeeeeeeee eeeeee eeeeeeeee eeeeeee. Me eeeeeeeeeeee eeeeeee, [Me8(μ-Me)8(η8-eee)8], eeeeee eeee eeeeee eeeeeee ee eeee eeeeeeeee eeee eeeeeeeeeeeeeeeeee eeeeee eeeeeee, eeeeeee, eee eeeeee. Meee eeeeeeee ee eeeee eeeeeeeee eee eeeeeeeeeee ee Meeeeee 8.8.8.8.8 (Meeee 8).[‌88‌‌88‌]

Meeee 8 Meeeeeeeee Meeeeeeeeeeee ee Meeeee eeee [Me8(μ-Me)8(η8-eee)8] eee Meeeee Meeeeeeee Meeeeee ee eee Meeeeeee Meeeeeeeee[‌88‌‌88‌]

Meeeeeeee Meeeee Meeeeeee Meeeeee, Meee Meeeeee Meeeee ee (%) Meeee (%) Mee
(8M,8M)-MMMM MeM8 MeMM, eeeeeee, 88°M (+) 88 88 [‌88‌]
(8M,8M)-MMMM eeeeeeeeeee eeeeeee, 88°M M >88 88 [‌88‌]
(8M,8M)-MMMM MeM8 MeMM, eeeeeee, 88°M M 88 88 [‌88‌]
(M)-Mee-MMMMM MeMM8 MeMM, 88°M M 88 888 [‌88‌]
(M)-MMMMM MeMM8 MeMM, 88°M M 88 888 [‌88‌]

e Meeeee eeeeeeeeee:

Meeeeee 8.8 eeeeee e eeeeeeeee ee eeee π-eeeeeeeee eeeee eeee eeee eeeeeeeeeee eee eeeeeee, eeeee eeee eeeeeeeeee eeeeee eee eeeeeeeeeeee. Me Meeeeee 8.8.8.8, eeee η8-eeeeeeee eeeeeeeee ee eeeeeeeee (Meeeee 88),[‌88‌] eeeee ee Meeeeee 8.8.8.8.8, eee eee ee eeeeee eeeeeeeee ee eee eeeeeeeee ee eeeeee eeeeeeeeeeeeeee ee eeeeeeee.[‌88‌]

Meeeee 88 Meeeeeeeeee ee ee Meee η8-Meeeeeee Meeeeee[‌88‌]

Meeeeeeee π-eeeeeeeee eee eeeeeeeee ee eeeeee ee Meeeeee 8.8. Meee eeeeeee ee π-eeeeeeeee eee eeeeeeee eeeeeee eeee eee eeeeeeeeeeee eeee ee eeeeeeeee eeeeeeeee eee ee eee eeee eeee ee eeeeeeeee. Mee eeeeeee, ee Meeeeee 8.8.8.8 e η8-eeeeeeeee eeeeeee ee eeee ee e eeeeeeeeeee ee eee eeeee- eee eeeeeeeeeeeeeee eeee-Meeeeeeeeee eeeeeeee ee eeeeee eeee ee e eeeeeeee eeeeee (Meeeee 88).[‌88‌] Meeeeeeeeeee ee eee eeeeee ee eeeeeeee ee e eee eeee ee eee eeeeeeee.

Meeeee 88 Mee Meeeeeeee-Meeeeeeee Meee-Meeeeeeeeee Meeeeeee ee Meeeeeeeee Meeee ee Meeeeeee Meeeeee[‌88‌]

Mee eeeeeeeee ee eeeeeeη8-eeeee eee η8-eeeeeeeeeee eeeeeeeee ee eeeeeeeee ee Meeeeeee 8.8.8.8 eee 8.8.8.88.8.8.8. Mee eeee eeeeee eeeeee eee eeeeee eeeeeeeeeeeeeeeeeeeeee eeeeeeeee ee eeeee eeeee (Meeeee 88).[‌88‌]

Meeeee 88 Meeeeeeee ee Meeeeeeeeeeeeeeee(MM)Meeee Meeeeeeee[‌88‌]

Me eeeeeeee, eeeee eeeeeee eee eee eeeeeeeeee ee eeeee eeeeeeeee eeee eeee eeeeee eeeeeeeeeee eeeeeeeeeee eeee ee eeeeeeeeeeeee eeeeeeee eeeeeeeeeeee eee eeeeeeeeeeeee eeeeeeee eee eeeeeeeee ee eeee eeeeeee ee eee eeeeee.

References