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1.3.5.1 Platinum(0)–Monoalkene Polydentate Complexes

DOI: 10.1055/sos-SD-001-00280

Ogawa, A.; Hirao, T.Science of Synthesis, (20011420.

Compared to platinum(II)monoalkene polydentate complexes (Section 1.3.5.2), there are very few examples of the corresponding zerovalent platinum complexes. Diphenyl(2-vinylphenyl)phosphine (111) is a useful ligand for the construction of platinum(0)monoalkene bidentate complexes.[‌182‌] The reaction of bis(η4-cycloocta-1,5-diene)platinum(0) (49) with two equivalents of phosphine 111 in toluene affords complex 112 in high yield (Scheme 69).

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