Science of Synthesis

Malacria, M.; Aubert, C.; Renaud, J.-L., Science of Synthesis, (2001) 1, 489.

Some low-valent cobalt–phosphine complexes such as tetrakis(trimethylphosphine)cobalt(0) (‌82‌) are used in stoichiometric or catalytic amounts as efficient mediators for one-pot Reformatsky-type reactions of halogen derivatives and α-halo phosphonates with carbonyl compounds.[‌218‌–‌221‌] The same cobalt complexes also proved effective in promoting Aldol-type reactions of α-halo ketones with carbonyl compounds.[‌222‌]

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‌Meeeee 88‌ Meeeeeeee ee Meeeeeee(eeeeeeeeeeeeeeeeee)eeeeee(8) ee Meeeeeeee ee Meeeee(MM) Meeeeeee[‌888‌]

Mee eeeeeeeeeeee ee eeeeeeeeeeeeeeeeee ee eeeeeeeeeeeeeeeeee eee eee eeeee eee eeeeeeeee ee eee eeeeeeeeeeeee eeeeeeee(eeeeeeeeeeeeeeeeee)eeeeee(8) eeeeeee; eeeeeee, ee eee ee eeee eeeee eee eeeeeeeee, ee eeeeeeee, eee eeeeeee eeeeeeeee.[‌888‌]

Meeeeeeeeeee Meeeeeeee

Meeeeeee(eeeeeeeeeeeeeeeeee)eeeeee(8) (‌88‌):[‌888‌]

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Meeeee M: Meeee MeMe8 (8 e, 88.8 eeee) eee Me8M (8 eM, 88.8 eeee) eeee eeeeeee eeee Me (8.8 e) ee MMM (88 eM). Meeee 88 e, eee eeeeeee eee eeeeeeeee eeee eeeeeee (88 eM) eee eeee eeeeeeee eeee eee eeeee eeee eeeeeeee. Mee eeee eee eeeeeeeeeeee eee eee eeeeeee eee eeeeeeee ee eeeeee ‌88‌; eeeee: 8.88 e (88%); ee 888°M (eee).

References