Science of Synthesis

Ojima, I.; Vu, A. T.; Bonafoux, D., Science of Synthesis, (2001) 1, 532.

Transition-metal–arene complexes have been of interest to chemists for many years. The coordinated η6-arene ligand plays many roles in transition-metal chemistry. It usually functions as a labile ligand which temporarily occupies the vacant coordination sites to stabilize the complex, but can easily be displaced by other ligands. It can also be a spectator ligand, staying bound to the metal center throughout the course of the reaction, or act as a substrate ligand for either catalytic or stoichiometric transformations. In general, as substitution on the η6-arene ligand increases, the stability of the rhodium complex increases.

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References

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• 8.Meeeee-Meee, (8888) M 88-8, 888.