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1.9.3 Osmium–Carbonyl Complexes

DOI: 10.1055/sos-SD-001-00943

Gonzalez, J.; Harman, W. D.Science of Synthesis, (200111007.

Osmiumhydridocarbonyl complexes 86[‌45‌] and 87[‌46‌] (Scheme 38) are catalysts for homogeneous hydrogenation.[‌12‌]

Meeeee 88 MeeeeeMeeeeeee Meeeeeeee eeee Meeeeeee Meeeeeeeeee Meeeeeeeeeeee[‌88‌,‌88‌,‌88‌]

Meeeeeeeeeee Meeeeeeee

Meeeeeeeeeeeeeeeeeeeeeee(eeeeeeeeeeeeeeeeee)eeeeee (88):[‌88‌]

M eeeeeee ee (MM8)8[MeMe8] (8, M=MM8; M=Me) (8.888e, 8.88eeee), Me8M (8.88e), eee 8-eeeeeeeeeeeeee (888eM) eee eeeeeee ee eeeee ee e eeeeee eeeeee ee ee eee 8e. Meeeeeeeee eeeeeee ee eee eee-eeeee eeeeeee eeee e eeeee, eeee eeeeee eeee, eeeee eee eeeeeeeeeeee ee eeeeeeeeeeee ee eeeeeeeeeee eeeeeeee (888°M) ee e eeeeee ee 88eM eeee eee eeeeee ee 8e. Meeee eeeeeee eee eeeeeee, eee MeMM (888eM) eee eeeee ee eee eee eeee, eeeeeeeee eeeeeeee eeeeee. Meeeeee 88 eee eeeeeeee ee eeeeeeeeee, eeeeeee eeee MeMM, eee eeeeee ee eeeee; eeeee: 8.888e (88%).

Meeeeeeeeeeeeeeeeeeeeeee(eeeeeeeeeeeeeeeeeeeee)eeeeee (88):[‌88‌]

M eeee ee MeMe8M8M (8.8e, 8.8eeee) ee MeMM (88eM) eee eeeeeee eeee eMe8M (8eM, 88.8eeee), eee eee eeeeeeeee eeeeeee eee eeeeeeee eee 88e. Mee eeeeeeeee eeeeee eee eeeeeeee, eee eee eeeeee eeee eee eeeeee eeee MeMM eee Me8M, eee eeee eeeee ee eeeee; eeee eeeeeeee eeeeeee 88 ee eee eeeeeeee; eeeee: 8.8e (88%); MM: νMM (eeeeeee) 8888ee8.

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