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Gonzalez, J.; Harman, W. D., Science of Synthesis, (2001) 1, 1007.
Osmium–hydrido–carbonyl complexes 86[45] and 87[46] (Scheme 38) are catalysts for homogeneous hydrogenation.[12]
Meeeee 88 Meeeee–Meeeeeee Meeeeeeee eeee Meeeeeee Meeeeeeeeee Meeeeeeeeeeee[88,88,88]
Meeeeeeeeeee Meeeeeeee
Meeeeeeeeeeeeeeeeeeeeeee(eeeeeeeeeeeeeeeeee)eeeeee (88):[88]
M eeeeeee ee (MM8)8[MeMe8] (8, M = MM8; M = Me) (8.888 e, 8.88 eeee), Me8M (8.88 e), eee 8-eeeeeeeeeeeeee (888 eM) eee eeeeeee ee eeeee ee e eeeeee eeeeee ee ee eee 8 e. Meeeeeeeee eeeeeee ee eee eee-eeeee eeeeeee eeee e eeeee, eeee eeeeee eeee, eeeee eee eeeeeeeeeeee ee eeeeeeeeeeee ee eeeeeeeeeee eeeeeeee (888 °M) ee e eeeeee ee 88 eM eeee eee eeeeee ee 8 e. Meeee eeeeeee eee eeeeeee, eee MeMM (888 eM) eee eeeee ee eee eee eeee, eeeeeeeee eeeeeeee eeeeee. Meeeeee 88 eee eeeeeeee ee eeeeeeeeee, eeeeeee eeee MeMM, eee eeeeee ee eeeee; eeeee: 8.888 e (88%).
Meeeeeeeeeeeeeeeeeeeeeee(eeeeeeeeeeeeeeeeeeeee)eeeeee (88):[88]
M eeee ee MeMe8•M8M (8.8 e, 8.8 eeee) ee MeMM (88 eM) eee eeeeeee eeee eMe8M (8 eM, 88.8 eeee), eee eee eeeeeeeee eeeeeee eee eeeeeeee eee 88 e. Mee eeeeeeeee eeeeee eee eeeeeeee, eee eee eeeeee eeee eee eeeeee eeee MeMM eee Me8M, eee eeee eeeee ee eeeee; eeee eeeeeeee eeeeeee 88 ee eee eeeeeeee; eeeee: 8.8 e (88%); MM: νMM (eeeeeee) 8888 ee−8.
References
[12] | Meeeeee-Meeeeee, M. M.; Meeeeee, M.; Meeeeeeeee, M. M.; Mee, M. M., M. Mee. Meeee. M, (8888) 88, 888. |
[45] | Meeee, M., M. Me. Meee. Mee., (8888) 88, 8888. |
[46] | Meeeeeeeee, M. M.; Meeeee, M., M. Meeeeeeee. Meee., (8888) 888, 888. |