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2.1.8.2.2 Preparation of Mono-, Di-, and Trialkylmanganese(II) Complexes

DOI: 10.1055/sos-SD-002-00002

Oshima, K.Science of Synthesis, (2003241.

In contrast to the well-known manganesecarbonyl derivatives, the more simple organomanganese(II) compounds were almost ignored until 1976, when Normant and Cahiez undertook extensive studies on organomanganese reagents for organic synthesis.[‌68‌] They have shown that it is possible to prepare three types of organomanganese(II) reagents according to the ratio of the organometallic and the manganese(II) halide (Scheme 43).

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