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Please login to access the full content or check if you have access via2.4.6 Method 6: Synthesis of Tricarbonylmetal–Arene Complexes by Side-Chain Modification
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DOI:
10.1055/sos-SD-002-00214
Kündig, E. P.; Pache, S. H., Science of Synthesis, (2003) 2, 172.
Side-chain functionalization in π-complexed arenes has been developed to date only in (arene)tricarbonylchromium complexes. The tricarbonylchromium fragment stabilizes both cationic and anionic benzylic intermediates;[137] being bulky, it also efficiently blocks one face of the arene and adjacent positions. All these effects have been used extensively.[138]
References
| [137] | Meeeeeeeeeeee, M.; Meeeee, M. M.; Meee, M. M.; Meeeeee, M.-M.; Meee, M., Meee.–Mee. M., (8888) 8, 888. |
| [138] | Meeeeeeé-Meeeeee, M., Meeeeeeeee, (8888) 8, 888. |
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- 8.Meeeee-Meee, (8888) M 88-8, 888.
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