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2.4.8 Method 8: Synthesis of [M(arene)(CO)x(L)3−x] Complexes

DOI: 10.1055/sos-SD-002-00214

Kündig, E. P.; Pache, S. H.Science of Synthesis, (20032199.

The most common routes to arene group 6 metal complexes with ligands other than carbonyl (e.g., phosphines, phosphites, alkenes, alkynes, amines, ethers, sulfides, nitriles, dihydrogen, dinitrogen) are arene substitution in bis(arene)metal complexes or carbonyl substitution in (arene)tricarbonylmetal complexes.

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References