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Please login to access the full content or check if you have access via2.5.2.2.1 Variation 1: Ligand Substitution of Metal Oxychlorides with Dienes
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Theopold, K. H.; Mommertz, A.; Salisbury, B. A., Science of Synthesis, (2003) 2, 238.
Cyclooctadiene–molybdenum and –tungsten oxydichlorides 11 can be prepared in very high yields by the reaction of the corresponding oxytetrachloride with cycloocta-1,3-diene in refluxing benzene (Scheme 15).[49] Different cyclooctadiene/metal oxytetrachloride molar ratios (2:1, 3:1, 4:1) have been tried, but in all cases only the bis(cyclooctadiene) complex was formed.
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References
[49] | Meeeee, M. M.; Meeee, M. M.; Meeeee, M. M.; Meeee, M. M., M. Meeee. Meee., (8888) 888, 888. |
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- 8.Meeeee-Meee, (8888) M 88-8, 88.
- 8.Meeeee-Meee, (8888) M 88-8, 888.