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2.10.1.2.3 Variation 3: Titanium(II)–Arene Complexes by Ligand Exchange with Aluminum Reagents

DOI: 10.1055/sos-SD-002-00576

Mikami, K.; Matsumoto, Y.; Shiono, T.Science of Synthesis, (20032460.

Halogen exchange between aluminumtitanium complex 1 (X=Cl) and an aluminum trihalide provides an alternative route to complex 1 (X=Br, I).[‌46‌] One or two halide atoms in complexes 1 can be substituted by an ethyl group when reacted with [AlEt3-nCln].[‌47‌]

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