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Please login to access the full content or check if you have access via2.10.2.1 Method 1: Titanium–Tetraene Complexes by Reaction of Tetrabutoxytitanium(IV) with Cyclooctatetraene
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Mikami, K.; Matsumoto, Y.; Shiono, T., Science of Synthesis, (2003) 2, 461.
Bis(cyclooctatetraene)titanium (4) is synthesized by the reaction of tetrabutoxytitanium(IV) with cyclooctatetraene and triethylaluminum [Ti(OBu)4/cot/Et3Al 1:10:10] at 80°C (Scheme 4).[52] Complex 4 is obtained as violet-red crystals from hot toluene in 80% yield. Tris(cyclooctatetraene)dititanium (5) is obtained similarly, as yellow crystals (80%), when the reactants [Ti(OBu)4/cot/Et3Al] are used in the molar ratio 1:2:10 (Scheme 4). Interconversion between [Ti(η6-cot)2] (4) and [Ti2(η6-cot)3] (5) occurs as shown in Scheme 4.[52] The structure of [Ti2(η6-cot)3] (5) has been determined by X-ray crystallography.[53]
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References
| [52] | Meeee, M.; Meeee, M., Meeee. Meee., (8888) 88, 888; Meeee. Meee. Mee. Me. Meee., (8888) 8, 888. |
| [53] | Meeeeeee, M.; Meeeeeeee, M., Meeee. Meee., (8888) 88, 888; Meeee. Meee. Mee. Me. Meee., (8888) 8, 888. |
| [54] | Meeeeeee, M.; Meeeee, M., M. Meeeeeeee. Meee., (8888) 88, M88. |
| [55] | Meeeeeee, M.; Meeeeeeee, M., Meeee. Meee., (8888) 88, 888; Meeee. Meee. Mee. Me. Meee., (8888) 8, 888. |
| [56] | Meeeeeee, M.; Meeeee, M. M., M. Meee. Mee., Meee. Meeeee., (8888), 888. |
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