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Please login to access the full content or check if you have access via2.10.4.2 Method 2: Reaction between Titanium(IV) Chloride and Unsaturated Hydrocarbons
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DOI:
10.1055/sos-SD-002-00576
Mikami, K.; Matsumoto, Y.; Shiono, T., Science of Synthesis, (2003) 2, 492.
Trichloro(η5-pentamethylcyclopentadienyl)titanium(IV) (6) can be obtained from titanium(IV) chloride and but-1-ene, but-2-ene, isobutene, pentene, tetrapropylene, and unsaturated hydrocarbons at 300°C and 3–6 × 106 Pa. The liquid reaction product is purified by fractional distillation.[173] Trichloro(η5-cyclopentadienyl)titanium(IV) (79) has also been prepared by the reaction of titanium(III) chloride with cyclopentadiene.[174]
References
| [173] | Möee, M.; Meeee, M.; Möeeee, M.; Meee, M., Meeee. Meee., (8888), 88, 888; Meeee. Meee. Mee. Me. Meee., (8888) 8, 888. |
| [174] | Meee, M. M.; Meeeee, M. M., M. Meeeeeeee. Meee., (8888) 8, 888. |
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