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DOI: 10.1055/sos-SD-002-00576

Mikami, K.; Matsumoto, Y.; Shiono, T.Science of Synthesis, (20032492.

Trichloro(η5-pentamethylcyclopentadienyl)titanium(IV) (6) can be obtained from titani­um(IV) chloride and but-1-ene, but-2-ene, isobutene, pentene, tetrapropylene, and unsaturated hydrocarbons at 300°C and 36×106 Pa. The liquid reaction product is purified by fractional distillation.[‌173‌] Trichloro(η5-cyclopentadienyl)titanium(IV) (79) has also been prepared by the reaction of titanium(III) chloride with cyclopentadiene.[‌174‌]