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Please login to access the full content or check if you have access via2.10.4.6 Method 6: Reaction between Tetraalkoxytitanium(IV) or Tetraamidotitanium(IV) Complexes and Cyclopentadienes
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DOI:
10.1055/sos-SD-002-00576
Mikami, K.; Matsumoto, Y.; Shiono, T., Science of Synthesis, (2003) 2, 494.
Tetrakis(dimethylamido)titanium(IV) reacts exothermally when treated with an excess of cyclopentadiene to give tris(dimethylamido)(η5-cyclopentadienyl)titanium(IV) (82, R1 = Me) (Scheme 38).[185] The alkoxy complexes [TiCp*(Ot-Bu)3],[184] [Ti(η5-MeC5H4)(OEt)3],[184] and [Ti(η5-Ind)(OBu)3] (Ind = indenyl)[186] are also synthesized from the corresponding tetraalkoxytitanium(IV) complexes by this method.
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References
| [184] | Meeeeeeeee, M. M.; Meeeee, M. M.; Meeeeeee, M. M.; Meeeeeeeeee, M. M., Mee. Meee. Meee MMMM, Mee. Meee., (8888), 888. |
| [185] | Meeeeee, M.; Meeeeee, M. M., Meeee. Meee. Meee. Meee., (8888) 8, 88. |
| [186] | Meeeeeee Meee Me., MM 888 888, (8888); Meee. Meeee., (8888) 88, 88888. |
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