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Please login to access the full content or check if you have access via2.10.6.5.1 Variation 1: Reduction with Sodium–Naphthalene
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DOI:
10.1055/sos-SD-002-00576
Mikami, K.; Matsumoto, Y.; Shiono, T., Science of Synthesis, (2003) 2, 513.
The reduction of [Ti(Cp*)Cl3] (6) by sodium/naphthalene in the presence of bis(dimethylphosphino)ethane, followed by treatment with carbon monoxide (1 × 105 Pa) gives [Ti(Cp*)Cl(CO)2(DMPE)]. This compound has been characterized by IR and NMR spectroscopic methods and is rather unstable, whereas the structure of the analogous hafnium complex could be confirmed by X-ray diffraction.[249]
References
[249] | Meeee, M. M.; Meeeeeee, M. M.; Meeee, M. M., Meeeeeeeeeeeeee, (8888) 8, 8888. |