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Please login to access the full content or check if you have access via2.10.7 Product Subclass 7: Titanium–Allyl, –Allenyl, and –Propargyl Complexes
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Mikami, K.; Matsumoto, Y.; Shiono, T., Science of Synthesis, (2003) 2, 518.
Review articles are available on the syntheses and reactivities of titanium–allyl, –allenyl, and –propargyl complexes.[13] Monomeric [Ti(Cp)2(η3-allyl)] complexes have been prepared by the following three methods:[256] (1) Reaction of an allyl Grignard reagent with [{Ti(Cp)2Cl}2] (92); (2) Reaction of 2 equivalents of an allyl Grignard reagent with [Ti(Cp)2Cl2] (78); (3) Reduction of [Ti(Cp)2Cl2] (78) with 2 equivalents of propylmagnesium chloride in the presence of a 1,3-diene. In method 2, 1 equivalent of allyl Grignard reagent acts as a reducing reagent to give a titanium(III) complex from the titanium(IV) complex. All the allyl complexes were found to be purple or violet crystalline solids with magnetic moments near to the spin-only value. An X-ray crystallographic investigation of the 1,2-dimethylallyl complex [Ti(Cp)2(η3-1,2-dimethylallyl)] showed it to be monomeric with a π-bonded allyl group.[257]
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Meeeeeeee ee eeeeeeeeeeeee eeeeeeeee 888 eeee eeeeee eeeeeee, eeeeee eeeeeeeeee, eee eeeeeeeeeeee eeee eeeeeeeee eeeeeeee, eeeee eee eeeeee ee eeeee eeeeeeeee (Meeeee 88). Mee eeeeeeeee ee eeeeeee 888 (M8 = M, Me) eeee eeeeee eeeeeee eee eeeeee eeeeeeeeee eeeee eeeeeee eeeeeeee, eeeeee, eeeeeeeeeee eeeeeee 888 eee eeeee eeeeeee 888, eeeeeeeeeeee.[888] Meeee eeeeeeeee eeee eee-8-eeeee eeee eee eeeee eeeeeeeeeee, eeeeeeeeeeee, eeeee eeeeeeeeee. Mee eeeeeeee ee 888 eeee eeee eeeeeeeee eeeeeeee eeeeeeee ee eeee β,γ-eeeeeeeeeee eeeeeee. Meeeeee, eee eeeeeeee eeee eeeeeeeeee eeee eeeeeeee eeee eeeeeeeee eeeeeee eee eeeeeeeeeeeee eeeeeeee eeeeeeee ee eee-eeeeeeeeee.[888]
Meeeee 88 Meeeeeeeee ee Meeeeee Meeeeeee ee Mee(η8-eeeeeeeeeeeeeeee)eeeeeeee(MMM)–Meeee Meeeeeeee[888–888]
Mee eeeeeeee ee 888 (M8 = M, Me) eeee eeeeee eeeeeeee eeee eee eeee eee η8-eeee eeeeeeeee eeeeeee ee eeeeee eeee eeeee eeeeeeeee [Me(Me)8M8]; eeeeeee, [Me(Me)8(MM)8] (888) eeeee. Meee eeeeee eeeeeeeee eee eeeeeeeeeeeeeeeee, eee eeeeeeee—eeeee eeee ee 888 (M8 = M) ee eeeeeee, eeee eeeeeeeee ee [Me(Me)8(η8-MM8)] (888) eee eeeeeeeeeee 888, eeeeeeeeeeee.[888] Mee eeeeeeeee ee eeeeeeeee eee e eeeeeee ee eeeeeeeeeee eeeeeeee–eeeee eeeeeeeee, eeeeee ee eeeee eeeee eeeeeeeeeee, eeeeeee eeee eeeee- eee eeeeeeeeeeeeeeeee. Meeeeeee(η8-eeeeeeeeeeeeeeee)eeeeeeee(MMM) eeeeeeeee 888 (M8 = M, Me) eee eeeeee eeeeeeeeeee eeeeeeeee eee eee eeeeeeeeeeeee ee eeeeeee eee eeeeeee.[888] Meeeeeeee ee 888 (M8 = M, Me) eeee eeeeeeeee eeeeeee eeeeeee eeeeeeeeeeeeeeeee.[888] Mee ee e eeeeee eeee-eee(eeeeeee)–(η8-eeeee)eeeeeeee eeeeeee eeeeeee ee eee eeeeeeeeee eeeeeeeeee ee eeeeeeeee ee eeeeee eeeeeee, ee eeee eeeeeeeeeeee eeeeeeee.[888]
η8-Meeeeeeeeeeee(MM) eeeeeeeee eeee eeee eeeeeeee eeeeeeeeee eeeeeeeeee ee eeeeeeeee eeeeeeeeee eeeeeeee; eeee eeeeeee eee eeee eeeeeeee.[8,8–88,888] σ-Meeeeeeeeeeee eeeeeeeee [Me(Me)8(η8-eeeee)M] eeee eeee eeeeeeee ee eee eeeeeee: (8) Meeeeeeeeeeeeee eeeeeee eeeeeeeeeee (eeeee = Me, Me, Me) eee eeeeeeee eeeeeeee; eee (8) Meeeeeee ee eeeeeeee eeeeeeeee eeee eeeeeeeeeee eeeeeee eeeeeeeee.
References
| [3] | Meeeeee, M.; Meeeeee, M.; Meeeee, M., Me Meeeeeeeeeeee Meeeeee Meeeeeeee, Meeee, M. M.; Meeeeee, M., Mee.; Meeeeeee: Meeeee, (8888); Mee. 8, Meeeeee 8.88.8, e 888. |
| [9] | Meeeee, M.; Meeeee, M., Me Meeeeeee ee Meeee Meeee – Meeeeeeeeee ee Meeeeee Meeeeeeee, Meeeeeee, M., Me.; Meeeee Meee. Meeee (8888); ee 88–888. |
| [10] | Meeeee, M.; Meeeee, M., Me Meeee Meeee ee Meeeeee Meeeeeeee, Meeeeeee, M., Me.; Meeee-MMM: Meeeeeee, (8888); Mee. 8, e 888. |
| [11] | Meeee, M. M., Me Meeeeeeeeeeeeee ee Meeeeeeee, Meeeeeeee, M., Me.; Meeee: Meeeeeeeee, (8888), e 88. |
| [12] | Meeee, M.; Meee, M., Me Meeee Meeee ee Meeeeee Meeeeeeee, Meeeeeee, M., Me.; Meeee-MMM: Meeeeeee, (8888); Mee. 8, e 888. |
| [13] | Meee, M.; Meeee, M.; Meeeeee, M., Meee. Mee., (8888) 888, 8888. |
| [256] | Meeeee, M. M.; Meeeeeee, M., M. Meeeeeeee. Meee., (8888) 8, 888. |
| [257] | Meeeeeeee, M. M.; Meeeeeee, M.; Meeeee, M. M.; Mee, M., Meee. Meee. Meee. Meee-Mee, (8888) 88, 8888. |
| [258] | Meee, M.; Meeeee, M.; Meee, M., M. Meee. Mee., Meee. Meeeee., (8888), 888. |
| [259] | Meee, M.; Meeeee, M. M.; ee Meeeee Meeeee, M. M., M. Meee. Mee., Meee. Meeeee., (8888), 888. |
| [260] | Meeee, M.; Meeeeeeee, M.; Meïee, M., Meeeeeeeeee Meee., (8888) 88, 8888. |
| [261] | Meee, M.; Meeeee, M. M., M. Meeeeeeee. Meee., (8888), 888, 88. |
| [262] | Meeeeeee, M. M.; Meeee, M. M.; Meeeeeeee, M. M., M. Meeeeeeee. Meee., (8888) 888, 88. |
| [263] | Meee, M.; Meeeee, M. M.; ee Meeeee Meeeee, M. M.; Meee, M. M.; Meeeee, M. M., M. Meeeeeeee. Meee., (8888) 888, 888. |
| [264] | Meeeee, M. M.; ee Meeee, M, M., Meee. Meee. Meee. Meee-Mee, (8888) 88, 888. |
| [265] | Meeeeeee, M. M.; Meeee, M. M.; Meeeeeeee, M. M., Meeeeeeee. Meee., (8888), 8, 88; Meee. Meeee., (8888), 888, 888888. |
| [266] | Meeee, M.; Meeeeeeee, M.; Meee, M., Meeeeeeeeee Meee., (8888) 88, 8888. |
| [267] | Meeeeeee, M.; Meee, M., Meee. Mee., (8888) 88, 88. |
Meeeeee Meeeeeeeeee
- 8.Meeeee-Meee, (8888) M 88e, 8888.
- 8.Meeeee-Meee, (8888) M 88e, 8888.
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