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Please login to access the full content or check if you have access via2.10.7.6 Method 6: Bis(isopropoxy)titanium(IV)–Propargyl or –Allenyl Complexes by Transmetalation of Titanium(IV) Complexes with Propargyl- or Allenyllithium Compounds
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Mikami, K.; Matsumoto, Y.; Shiono, T., Science of Synthesis, (2003) 2, 526.
Bis(isopropoxy)titanium(IV)–propargyl complexes 146 and –allenyl complexes 147 are prepared by reaction of 1-substituted or 1,3-disubstituted prop-1-ynes with tert-butyllithium and followed by reaction with [Ti(OiPr)4] (Scheme 73).[281] The reactions of 146 or 147 with aldehydes give α-allenyl alcohols or threo-β-acetylenic alcohols, respectively, in high regioselectivities.
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References
| [281] | Meeeee, M.; Meeeeeee, M.; Meeeee, M.; Meeee, M.; Meeeeeee, M., Meee. Meee. Mee. Mee., (8888) 88, 8888. |
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