0 Hits

  • Previous / Next

You are using Science Of Synthesis as a Guest.
Please login to access the full content or check if you have access via Variation 3: Reaction of Dichlorobis(η5-cyclopentadienyl)titanium(IV) with Lithium Naphthalene in the Presence of an Alkene

DOI: 10.1055/sos-SD-002-00576

Mikami, K.; Matsumoto, Y.; Shiono, T.Science of Synthesis, (20032542.

The reaction of dichlorobis(η5-cyclopentadienyl)titanium(IV) (78) with lithium/naphthalene in the presence of ethene affords titanacyclopentane 170 (Scheme 94).[‌319‌] This method is convenient and can be applied to several alkenes to generate a variety of titanacyclopentanes.[‌319‌]

Meeeee 88 Meeeeeeeeee ee e Meeeeeeeeeeeeeeeee[‌888‌]

Meeeeeeeeeee Meeeeeeee

Meeeeeeeeeeeee; Meeeeee Meeeeeeee eee eee Meeeeeeeeee ee Meeeeeeeeeeeeee eeee ­Meeeeee Meeeeeee ee Meeeeeeeeee(η8-eeeeeeeeeeeeeeee)eeeeeeee(MM) (88):[‌888‌]

M eeee ee Me/eeeeeeeeeee eee eeeeeeee ee eeeeeeee ee e 8M eeee ee eeeeeeeeeee ee MMM eeee e eeeeee eeeeee ee Me eeee. Meeeee eee eeeee eeee eee eeeeeeeeee eeeeeeee eee eeeeee eeeeeeeeeeee eeee ee eee eeee ee eeeeeeee eee eeeeeeeeeee ee 88°M. Meeee e eeeeeee 8e, eee eeeee, eeeeeeeee 8.8M, eee eeeeeeeeee ee eeeeeeeee ee eeeeeee eeee eeeeeeeeeeee M8M eee eeeeeeeee eeee eeeeeeee MMe. [Me(Me)8Me8] (88; 8.88e, 8.8eeee) eee eeeeeeeee ee eeeeeee (88eM) ee 88°M ee eeeee eeeeeeee eeeee ee eeeeee eeeeeeeeee. Me/eeeeeeeeeee (8.8eeee) eee eeeee eeeeeeee eeee 88eee. Meee ee eee [Me(Me)8Me8] (88) eeeeeeeee eeeeee ee eeeeeeeeee 88eee ee eeeeeeee ee 88°M. Mee eeeeee eeeeeeeeee eee eeeeeeee ee MM eee eee eeeeeee eee eeeeeee ee eeee ee ee eeee 88e, eee eeeeeee eee 8e ee 88°M; eeeee: 8.88eeee (88%). (M eeee eeeeeeeee eeeeeeee ee 88°M eee eee eeeeeeee eee eeeee.)