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2.10.9.2.3 Variation 3: Reaction of Dichlorobis(η5-cyclopentadienyl)titanium(IV) with Lithium Naphthalene in the Presence of an Alkene

DOI: 10.1055/sos-SD-002-00576

Mikami, K.; Matsumoto, Y.; Shiono, T.Science of Synthesis, (20032542.

The reaction of dichlorobis(η5-cyclopentadienyl)titanium(IV) (78) with lithium/naphthalene in the presence of ethene affords titanacyclopentane 170 (Scheme 94).[‌319‌] This method is convenient and can be applied to several alkenes to generate a variety of titanacyclopentanes.[‌319‌]

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