0 Hits

  • Previous / Next

You are using Science Of Synthesis as a Guest.
Please login to access the full content or check if you have access via Method 3: Photolysis of Bis(η5-cyclopentadienyl)dimethyltitanium(IV) in the Presence of an Alkyne

DOI: 10.1055/sos-SD-002-00576

Mikami, K.; Matsumoto, Y.; Shiono, T.Science of Synthesis, (20032544.

Photolysis of bis(η5-cyclopentadienyl)dimethyltitanium(IV) (85) produces a titanocene intermediate, which is trapped with diphenylacetylene to give titanacycle 132 in 3550% yields (Scheme 96).[‌234‌,‌324‌]

Meeeee 88 Meeeeeeeeee ee e Meeeeeeeeee ee Meeeeeeeee[‌888‌,‌888‌]