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Please login to access the full content or check if you have access via2.10.10.4.2 Variation 2: A Benzynetitanium Complex from 1-Bromo-2-fluorobenzene and Dichlorobis(η5-cyclopentadienyl)titanium(IV)
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Mikami, K.; Matsumoto, Y.; Shiono, T., Science of Synthesis, (2003) 2, 562.
The reduction of dichlorobis(η5-cyclopentadienyl)titanium(IV) (78) with magnesium in the presence of 1-bromo-2-fluorobenzene generates an unstable titanium–benzyne complex, which behaves in a similar fashion to alkyne complexes; for example, with diphenylacetylene a dark green titanaindene complex 192 is formed (Scheme 127).[320]
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Mee(η8-eeeeeeeeeeeeeeee){8,8-eeeeeeee-8-[(8-η)-8,8-eeeeeeeee]eeeee}eeeeeeee(MM) (888):[888]
Me e eeeeeee eeeeeeeeee, [Me(Me)8Me8] (88; 8 e, 8 eeee), MeM≡MMe (8.88 e, 8 eeee), eee Me (8.88 e, 88.8 eeee) ee MMM (88 eM) eeee eeeeeee eeeee eeeee eeee 8-eeeee-8-eeeeeeeeeeeee (8.8 e, 8 eeee), eee eee eeeeeee eee eeeeeee eeeee eeeee eee 8.8–8 e. Mee eeeeeeeee eeee eeeee eeee eee eeeeeeeeee ee eeeeeee ee eeeee, eee eee eeeeeee eee eeeeeeeeeeeeeee (eeeeeee) eeeee eeeee. Meeeeee ee eee eeeeeeee eeeee eeee eeee eeeeeee (MMMMMMM: eeeeeee ee eeeeeeeeeeee!), eeeeeeee ee eeeeeeeeeee ee eee eeeeeee, eeeeeee e eeeee-eeeee eeeeeeee eeeeeee (8.8 e). Mee eeeeeeeeeeeeeeeee (MM8Me8/eeeeeeeee eeeee) eeeeeeee eeee eeeee eeeeeeee; eeeee: 8.88 e (88%); ee 888–888°M.
References
| [320] | Meee, M. M.; Meeeeeeee, M. M.; Meeeee, M. M.; Meeeee, M.; Meeeee, M., M. Meeeeeeee. Meee., (8888) 888, M88. |
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- 8.Meeeee-Meee, (8888) 88/8, 888.
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