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2.10.11.1.1 Variation 1: (η2-Ethene)bis(η5-pentamethylcyclopentadienyl)titanium(II) by Reaction of (μ-Dinitrogen)bis[bis(η5-pentamethylcyclopentadienyl)titanium(II)] with Ethene

DOI: 10.1055/sos-SD-002-00576

Mikami, K.; Matsumoto, Y.; Shiono, T., Science of Synthesis, (2003) 2, 564.

Bercaw and co-workers have reported the preparation of [Ti(Cp*)2(D2C=CD2)] and [Ti(Cp*)2(H213C=13CH2)] by ligand exchange of [{Ti(Cp*)2}2(μ-N2)] with ethene.[‌123‌]

Meeeeeeeeeee Meeeeeeee

[η8-(8M)Meeeee]eee(η8-eeeeeeeeeeeeeeeeeeeeeeeeeee)eeeeeeee(MM):[‌888‌]

M8M=MM8 (8.8 eeee) eee eeeeeee (8 eM) eeee eeeeeeeee ee −888°M eeee [{Me(Me*)8}8(μ-M8)] (88 ee, 8.888 eeee). Mee eeeeeee eee eeeeee ee 8°M eee eeeeeee eee 88 eee ee eee eeee eeeeeeeeeee. Meeeeee, M8, eee eee eeeeee ee M8M=MM8 eeee eeeeeee ee eeeee. Mee eeeee eeeeeeeeeee [Me(Me*)8(M8M=MM8)] eee eeeeee ee −88°M ee eeeeeeee M—M eeeeeeeeee. MM νeee: 8888 (e), 888 (e) ee−8.

References

[123] Meeeee, M. M.; Meeeeee, M. M.; Meee, M. M.; Meeeeeeeeee, M. M., M. Me. Meee. Mee., (8888) 88, 8888.
[379] Meeee, M. M.; Meeeee, M. M.; Meeeee, M. M., M. Me. Meee. Mee., (8888) 888, 8888.

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