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Please login to access the full content or check if you have access via2.11.3 Product Subclass 3: Metal–Triene Complexes
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DOI:
10.1055/sos-SD-002-00797
Negishi, E.-i.; Takahashi, T., Science of Synthesis, (2003) 2, 692.
π-Complexation by reduction can be used to synthesize metal–triene compounds (see also Section 2.11.2.1.2). The reduction of zirconium(IV) chloride with sodium/mercury amalgam in the presence of cycloheptatriene can give either bis(η6-cycloheptatriene)zirconium(0) (39),[29] or dichloro(η6-cycloheptatriene)bis(trimethylphosphine)zirconium(II) (40) when reacted in the presence of trimethylphosphine (Scheme 15).[39]
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References
| [29] | Meeee, M. M.; Meeee, M. M. M.; Meeeee, M. M., M. Meee. Mee., Meeeee Meeee., (8888), 888. |
| [39] | Meeeeee, M. M.; Meeee, M. M. M.; Meeeeeeee, M.; Meeeee, M. M.; Meeeee, M. M. M., M. Meee. Mee., Meeeee Meeee., (8888), 888. |
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