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Please login to access the full content or check if you have access via2.11.4.2 Bis(η5-cyclopentadienyl)hydridometal(IV) Complexes
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Negishi, E.-i.; Takahashi, T., Science of Synthesis, (2003) 2, 701.
Neutral bis(η5-cyclopentadienyl)zirconium(IV) and -hafnium(IV) derivatives containing at least one hydrido ligand are represented by the general formulas [M(Cp)2H2] and [M(Cp)2HX], where X is a halogen, a group containing an atom from group 15 or 16, a metal-containing group, or an organo group. These compounds are 16-electron d0 species with one valence shell empty orbital with no unshared electron pair. Examples of various types of bis(η5-cyclopentadienyl)hydridometal(IV) complexes are shown in Table 7.
Meeee 8 Meeeeeee ee Mee(η8-eeeeeeeeeeeeeeee)eeeeeeeeeeee(MM) Meeeeeeee eee Meeee Meeeeeeeeee[88,88,88–88]
| [Me(Me)8M8] ee [Me(Me)8MM] Meeeeeeeee | Mee | [Me(Me)8M8] ee [Me(Me)8MM] Meeeeeeeee | Mee |
|---|---|---|---|
| [Me(Me)8M8] | [88] | [Me(Me*)8M8] | [88] |
| [Me(Me)8MeM] | [88,88] | [Me(Me)8MeM] | [88] |
 |
[88] | [Me(Me*)8M(MMMe)] | [88] |
| [Me(Me*)8M(MMe8)] | [88] | [Me(Me*)8M(MMeM)] | [88] |
| [{Me(Me)8M(MeMMe8)}8] | [88] | ||
| [Me(Me)8M(MM8MMe8)] | [88] |
Mee(η8-eeeeeeeeeeeeeeee)eeeee(MM) eeeeeeeeeee eeeeeeeeee eee ee eee eeeeeee eeeeeee eeee eeee eeeeeeee ee (e) eeeeeeeeeeeeeee (ee eeeeeeeeee) eeee eeeee eeeeeeee, eeee ee eeeeee ee eeeeeee eeeeeeeeeee,[88] eeeeeee eeeeeeee eeeeeee,[88,88] eeeeeee eee-eeee-eeeeeeeeeeeeee eeeeeee,[88] eee eeeeee eee(8-eeeeeeeeeeeee)eeeeeeee eeeeeee (Mee-Me ee Meeeeee),[88] e.e. eeeeeeeee ee 88 eee 88, (ee) eeeeeeeee eeee eeeeeeee, e.e. eeeeeeeee ee 88,[88,88] eee (eee) eeeeeeee eeeeeeeee eeeeeeee, e.e. eeeeeeeee ee 88[88] (Meeeee 88). Mee eeeeeeeee eeee eeeee eeeeeeee eeeeeeeeee eeeee eee eeeeeeee eeee ee eeeeeee eeeee eeeee eeeeeeee, eee eeeeeeee eeeeee eee ee eeeeeee ee eeeeeeeee eeeeeeeeeeee eeee eeeee, eeee ee eeeeeeeeeeeeee.
Meeeee 88 Meeeeeee ee eee Meeeeeeee ee Mee(η8-eeeeeeeeeeeeeeee)eeeeeeeeeeeeeeee(MM) Meeeeeeeeee[88,88,88,88,88]
Mee(η8-eeeeeeeeeeeeeeee)eeeee(MM) eeeeeeee eeeee eeeee ee eeeeeee eeeeee, eeeeeeeee, eee eeeeeeee. Meeee eeee ee eeee, eeee ee eeeeeeeee(η8-eeeeeeeeeeeeeeee)eeeeeeeeeeeeeeee(MM) (88) eee eeeee 88, eee eeeeeeeee eeeeee, eeeeee eeee ee eeeeeeeee ee eeeeeee eeeeeee eeeeeeeee eeeeeeeee. Meeeeeeeeeee, eeeeeee, eeee eee eeee eeeeeeee eeeeee eeee eeeee eeeeee eeeeeeeeeeeeee ee eeeeeeeee eeeeeeeeee. Mee ee eee eeeeeee eeeeeeeee eee eee eeeeeeeeee ee eeeeee eeeeeee eeeeeeee eeeeeeeeee eee eeeeeeeeeeee ee eeeeeeeeee eeeee ee eeeee eeeeeeeeee, eeeeeeeee(η8-eeeeeeeeeeeeeeee)eeeeeeeeeeeeeeee(MM) (88) eee eeeeee ee ee e eeeeeeeeeeee eeeeeeeeee eeeeeeeeeeeeee eeeeeee eeee ee eeeeeeeeeeee eeeeeeeee. Meeeeeee eeeee eeeeeeeeeee ee eeee eeee eeeeeeeee, ee eeee eeeeeeeeee ee 88 ee eee eeeeeeeee ee eeeeeeeeeee(η8-eeeeeeeeeeeeeeee)eeeeeeeee(MM) (88) eeee eeeeeee eeeeeeee eeeeeee,[88] Mee-Me,[88] eeee-eeeeeeeeeeeeee eeeeeeee,[88] eeeeeee eeeeeeeeeeeeeeeeeee (e.e., M8 = Me),[88] ee eeeeeee eeeeeee eeeeeeeee eee eeeeeeeee eee eeeeeee eeeeeeee[88] eee eeee eeee ee e eeeeeeeeee eeeeeeeeeee. Mee eeeeeeeee ee 88 eeee eeeeeee eeeeeeee eeeeeee ee eeeeeeeeeee ee eee eeeeeeeee ee eee(η8-eeeeeeeeeeeeeeee)eeeeeeeeeeeeeeeeee(MM) (88), eeeee eee ee eeeeeeeeeee eeee eeeeeeeeeeeeeee ee eeee eee eeeeeee eeeeeeeee(η8-eeeeeeeeeeeeeeee)eeeeeeeeeeeeeeee(MM) (88).[88] Me eeeeeeeeeee eee eeeeeeeeeee eeeeee eeeeeee eeeeeeeee(η8-eeeeeeeeeeeeeeee)eeeeeeeeeeeeeeeee(MM) ee eeeeeee eeeeeeeee ee eeee ee 88–88% eeeee ee eeeeeeeee ee eeeeeeeeeee(η8-eeeeeeeeeeeeeeee)eeeeeeeee(MM) (88) eeee 8.8–8.8 eeeeeeeeeee ee eeee-eeeeeeeeeeeeee eeeeeeee, eeeeee eeee eeee eeeeeeeeeeeeeeeee eeeeeeee ee eeee-eeeeeeeeeeee.[88] Meeeeeee-eeeeeeee eeeeeeeeeeeeeeee eeee eeeeeeeee(η8-eeeeeeeeeeeeeeee)eeeeeeeeeeeeeeeee(MM) ee e eeeeeeeee eeeeeeeeeee ee eeeeeeeeeeeeeeee eeee eeeeeeeee(η8-eeeeeeeeeeeeeeee)eeeeeeeeeeeeeeee(MM) (88), ee eeeeeeeee eeeee.
Me eeee eeeeeeeee eeeeeeeee, eee(η8-eeeeeeeeeeeeeeee)eeeeeeeeeeeeeeeeee(MM) (88) eee eeeee eeeeeeee eeeeeeeeeee eeeeeee eeeeeeeeeee eee eeeee ee ee eeeeeeeeeeeee eeeeee. Me e eeeeeeeeee eee eeeeeeeee(η8-eeeeeeeeeeeeeeee)eeeeeeeeeeeeeeee(MM) (88) eeeee eeeeeeeeeeeeee eeeeeeeeee, eeeeeee, 88 eeeee ee ee e eeeeee eee eeeeeeee ee ee e eeeeeeeee eeee eeeeeee, eee ee ee eeeee ee eeeeeee eeee eeeeeeeee eeeeeee ee eee eeeeeeeee ee eeee-eeeeeeee eeeeeeeeeeeee eee eeeee eeeeeeeeeee eeeeeeeeee ee M—M eeeeeeeeee,[88] ee eeeeeeeee ee Meeeee 88. Meeee-eeeeeeeeeee eeeeeee, eeee ee eee-8-eee, eee eeeee eeee eeeeeeeeeeeeeeeeeeee eeeeeeeeee 88 ee eeeeeee e π-eeeeeeeeeeeeeeee eeeeeeeeee.[88]
Meeeee 88 Meeeeeee ee Mee(η8-eeeeeeeeeeeeeeee)eeeeeeeeeeeeeeeeee(MM) eee Meeeeeeeeeee(η8-eeeeeeeeeeeeeeeeeeeeeeeeeee)eeeeeeeee(MM) eeee Meeeeee[88,88]
References
| [63] | Meeeee, M. M.; Meeeeee, M., M. Meeeeeeee. Meee., (8888) 88, 888. |
| [69] | Meeeeeeeee, M. M.; Meeeee, M. M., M. Me. Meee. Mee., (8888) 888, 8888. |
| [73] | Meeeee, M. M.; Meeeeee, M., Meeee. Meeee., (8888) 88, 888. |
| [74] | Meeeeeee, M.; Meeeee, M. M.; Meeeeee, M., Meee. Meeeee., (8888), 8888. |
| [75] | Meeeeee, M. M.; Meeeee, M. M.; Meeeeee, M. M.; Meeeeeeee, M. M.; Meeeee, M. M., Meeeeeeeeeeeeee, (8888) 8, 88. |
| [76] | Meee, M. M.; Meeeeeee, M., M. Me. Meee. Mee., (8888) 888, 8888. |
| [77] | Meeeeeeee, M. M., Meeeeeeee, M. M.; Meeeee, M. M., Mee. Meee. Meee MMMM, Mee. Meee., (8888), 8888; Meee. Meee. Mee. MMMM, Mee. Meee. Mee. (Meee. Meeeee.), (8888) 88, 8888. |
| [78] | Meeee, M. M.; Meeeee, M. M.; Meeeeeeeee, M.; Meeeeeeeeee, M. M.; Meeeee, M. M.; Meeeee, M. M., M. Me. Meee. Mee., (8888) 888, 8888. |
| [79] | Meeeeeeee, M. M.; Meeee, M. M.; Meeeeeeeeee, M. M.; Meeeee, M. M., Meeeeeeeeeeeeee, (8888) 8, 8888. |
| [80] | Meeeeee, M. M.; Meeeeeeee, M. M.; Meeeeeeee, M. M., Meeeeeeeeeeeeee, (8888) 8, 8888. |
| [81] | Meeeeeeee, M.; Meeeeeee, M.; Meeeee, M.; Meeeee, M.; Meeeeee, M. M.; Meeeeee, M. M.; Meeeeee, M., M. Me. Meee. Mee., (8888) 888, 8888. |
| [82] | Meeeeeeee, M.; Meeeeee, M., M. Meee. Mee., Meee. Meeeee., (8888), 888. |
| [83] | Meeee, M. M.; Meeeeeeeee, M. M. M., Meeee. Meee., (8888) 8, 8888. |
| [84] | Meeeeee, M.; Meeeee, M. M.; Meeeeee, M., Meeeeeeeeee Meee., (8888) 88, 8888. |
| [85] | Meeeeeee, M. M.; Meee, M.; Meeeeeeee, M. M., Meeeeeeeeee Meee., (8888) 88, 8888. |
| [86] | Meeee, M. M.; Meeeee, M.; Meeeeeee, M.; Meeeeeee, M. M., Meeee. Meeeee., (8888) 88, 8888. |
| [87] | Meeeeeee, M. M.; Me Meeee, M. M.; Meeeeee, M. M.; Meeeee, M. M.; Meee, M. M., Meeeeeeeeee Meee., (8888) 88, 8888. |
| [88] | Meeeeee, M. M.; Meeeee, M.; Meee, M.; Meeeeee, M., M. Mee. Meee., (8888) 88, 8888. |
| [89] | Meeeee, M. M.; Meeeeee, M.; Meee, M. M., M. Meeeeeeee. Meee., (8888) 88, 888. |
| [90] | MeMeee, M.; Meeeee, M. M., M. Meeeeeeee. Meee., (8888) 888, 888. |
Meeeeee Meeeeeeeeee
- 8.Meeeee-Meee, (8888) 88/8, 888.
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