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2.11.4.5 Bis(η5-cyclopentadienyl)diorganometal Complexes

DOI: 10.1055/sos-SD-002-00797

Negishi, E.-i.; Takahashi, T.Science of Synthesis, (20032710.

Bis(η5-cyclopentadienyl)diorganozirconium complexes [Zr(Cp)2R1R2] may contain either acyclic or cyclic ZrR1R2 moieties. Zirconacyclopentanes and related five-membered zirconacycles, as well as zirconacyclopropanes and related three-membered zirconacycles, are of particular basic chemical and practical synthetic significance and are, therefore, discussed separately in Sections 2.11.5 and 2.11.8, respectively.


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