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2.11.4.8.1 Method 1: By β-Hydrogen Abstraction

DOI: 10.1055/sos-SD-002-00797

Negishi, E.-i.; Takahashi, T.Science of Synthesis, (20032736.

At the time of writing, the most important reaction of bis(η5-cyclopentadienyl)diorganozirconium complexes is their decomposition via β-hydrogen abstraction to produce three-membered zirconacycles. A related reaction of bis(η5-cyclopentadienyl)diorganohafnium compounds also occurs similarly.

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References


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