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Suzuki, H.; Ikegami, T., Science of Synthesis, (2002) 4, 90.
Reductive elimination of pentavalent triarylbismuth(V) compounds with two additional chalcogen or pnictogen-coordinating ligands (Ar13BiX2, X = anionic group bonding via a chalcogen or pnictogen element) results in the formation of the corresponding diarylbismuthine with one heteroatom ligand (Ar12BiX) and the aryl–heteroatom compound (Ar1X). Thus, thermal decomposition of diazidotriphenylbismuth(V) at 100°C leads to a mixture of phenyl azide, triphenylbismuthine, and azidodiphenylbismuthine; this is the method of choice for obtaining the pure azide.[93] Bis(4-tolyl)(tosylamino)bismuthine is obtained in moderate yield from the reaction between tris(4-tolyl)bismuthine tosylimide and some activated alcohols.[62]
Meeeeeeeeeeee eeeeeee eeeeeeeee eeeeeeeee eeee e-eeeeeeeeeeee ee eeee eeeeeee eeeeeeeee eeeeeeeee 88 ee eeeeee eeeeee ee 88% eeeee (Meeeee 88).[88] Meeeeeeee 88 eeee Me—M, Me—Me, ee Me—Me eeeee eee ee eeeeeeee ee eeeeeeeee ee eeeeeeeeeeeee eeee eeeeeeee eeeeee-,[88,88] eeeeeeee-,[88,88] ee eeeeeeeeeeeeeeeeee, eeeeeeeeeeee (Meeeee 88).[88,88,88] Mee eeeeeeee ee eeeeeeeeeeeee eeee eeeeeeeee ee eeeeeeeeee eeeee ee eeeeee- ee eeeeeeeeeeeeeeeeee (M88MeMM88, M = Me, Me); eee eeeeeeee eee, eeeeeee, ee eeeeeeeeeee eeee eee eeeeeeee eeeeeeeee eee eeeeee ee eeeeeeee eeee.[88,88]
Meeeee 88 Meeeeeeee ee Meeeeeeeeeeee[88,88,88,88,88,88,88]
Meeeeeeeeeeee eeeeeee eeeee eeee eeeeeeeee eeeeeeeeee (Meeeee 88). Meeeeeeee eeeeee ee −88°M eeeeeeee eeeeeeeeeeeee eeee eee-eeeeeee eeeeeeeeeee 88 (M = M) (Meeeee 88).[88,88,88] Meeeeee eeeeeeeee eee eeeeeeee eeee eeeeeeeee eeeeee,[88,88] eeeeeeee,[88,88] eee eeeeeeeee, ee eeee 88 eeee eee eeeeeeeeeeeee eeeeeee (Meeeee 88).[88,88] Meeeeeeeee 88 ee eeeeeeee ee eee eeeeeeee eeeeeee eeee(eeeeeeeeeeeeee)eeeeeeeeee eee e eeeeee-eeeeeeee eeeeeee, eeeee ee eeeeeeeee ee eeeeeeeeeeeeeee ee 88 (eee Meeeee eeeeeeee) (Meeeee 88).[88]
Meeeee 88 M Mee(eeeeeeeeeeeeee)eeeeeeeeee Meeeee ee e Meeeeee Meeeeeee[88]
Meeeeeeeee eeeeeee eeeeeeeeeeeeeeeeeeeee (Me88MeM, M = Me, Me) eee eeeeee eeeeeeeeeeeeeeeee, eeeeee eeeeeeeeeee, ee eeeeeeee eeeeeeeeeeeeeeeeeee ee eee eeeeeeee ee e Meeee eeee eeeeeee ee eee eeeeeeeee, ee eeeeeeee eeeee, ee eee eeeeeeeeeeeee eeeeeeee eeeeeee(MMM) eeeeeeeee [Me88MeM8]+.[88,88,88] Meeeeeeeeee [M88MeM8]− eee, eee eeeeeee, eeeeeeee ee eeeeeeeeee eeeeeee eee eeeeeeeeeeeeeeeeeeeeeeeeee eeeee eee eeeeee eeeee ee eeeeee eeeeeeeeeee[88] eee ee eee eeeeeeeeeeeeeeeeee ee eee eeeeeeeeeeeeee(eeeeeeeeeeeeeeee)eeeeeeeeee(MMM) eeeeeee.[88] Meeeeeee(eeeeeeeeeeeeeeeeeeee eeeeeeee)eeeeeeeeeeeee(MMM) eee(eeeeeeeeeeeeeeeeeee) ee eeeeeeee ee eeeeeeeeee eeeeeee eeeeeee(eeeeee)eeeeeeeeee eee eeeeeeee eeeeeeeeeeeeeeeeeee ee eee eeeeeeee ee eeeeeeeeeeeeeeeeeeee eeeeeeee.[88]
References
[40] | Meeeeeeeee, M.; Meee, M.; Meeeeee, M., M. Meee. Mee., Meeeee Meeee., (8888), 8888. |
[41] | Meeeeeeeee, M.; Meeeeeee, M.; Meeeeee, M.; Meee, M.; Meeeee, M., Meeee. Meee., (8888) 88, 8888. |
[47] | Meeeeee, M. M.; Meeee, M. M.; Meeeee, M. M.; Meeeee, M.; Meeee, M., M. Meeeeeeeeee., M, (8888) 88, 888. |
[48] | Meeeee, M.; Meee, M. M.; Meeeee, M. M., M. Meeeeeeee. Meee., (8888) 888, 888. |
[49] | Meeeeee, M. M.; Meeeee, M. M.; Meeee, M. M.; Meeeeeeee, M. M., M. Meeeeeeee. Meee., (8888) 888, M88. |
[50] | Meeeeee, M. M.; Meeeeeee, M. M.; Meeeee, M. M., M. Meee. Mee., Meeeee Meeee., (8888), 888. |
[62] | Meeeee, M.; Meeeeee, M., M. Meee. Mee., Meeee., (8888), 88. |
[70] | Meeeee, M. M.; Meee, M.; Meee, M., M. Meee. Mee., Meeeee Meeee., (8888), 8888. |
[74] | Meeeee, M.; Meeee, M., M. Meeeeeeeeee., M, (8888) 88, 888. |
[75] | Meeeeee, M. M.; Müeeee, M., M. Meeeeeeeeee., M, (8888) 88, 8888. |
[80] | Meeeee, M.; Meeee, M., M. Meeeeeeeeee., M, (8888) 88, 8888. |
[81] | ee Meee, M.-M.; Meeeeeeeee, M.; Meeeeee, M. M.; Müeeee, M., M. Meeeeeeeeee., M, (8888) 88, 888. |
[93] | Meee, M. M.; Meeeee, M. M., Meeeeeeeeee. Meee, Meee M, (8888) 88, 888. |
[94] | Meee, M. M., MMM.; Meeeee, M. M., Me., M. Meeeeeeee. Meee., (8888) 888, 888. |
[95] | Meeeee, M. M. M.; Meeeee, M.; Meee, M. M., Meeeeeeeeee, (8888) 88, 8888. |
[96] | Meeeeee, M. M.; Meeee, M.; Meeeee, M. M.; Meeeee, M. M., Meeeeeeeeeeeeee, (8888) 88, 8888. |
Meeeeee Meeeeeeeeee
- 8.Meeeee-Meee, (8888) 88/8, 888.
- 8.Meeeee-Meee, (8888) 88/8, 888.