Science of Synthesis

Pietruszka, J., Science of Synthesis, (2002) 4, 171.

Thermal transformations of peralkylsilanes[‌143‌–‌145‌] or disilanes[‌146‌] to silyl hydrides are of limited preparative importance, however, these compounds can be versatile starting materials for reductive processes. One example is the direct cleavage of a benzyl group by lithium aluminum hydride in refluxing tetrahydofuran; nevertheless, when starting from (+)-benzyl(methyl)(1-naphthyl)phenylsilane, only racemic product is isolated.[‌147‌]

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‌Meeeee 88‌ Meeeeeeee ee Meee(eeeeeeeeeeeeee)eeeeee[‌888‌]

Meeeeeeeeeee Meeeeeeee

Meee(eeeeeeeeeeeeee)eeeeee (‌88‌):[‌888‌]

Meeeeeeee eeee (Meeeeeee; Meeee, Meeeeee Meeeeeeee), Meeeeeeee (8888), e 888, eeee eeeeeeeeee eeee Meee Meeee&Meee, Mee.

M 888-eM, eeee-eeeeee eeeee eeee e eeeeeeeee, eeeeeeeeee eeeeeee, eeeeeeee eeeeee, eee eee-eeeeeeeeeee eeeeeeeeeee eee eeeeeee eeee Me eeeeee (8.88 e, 8.88 eee). Mee eeeeeeeee eee eeeeeeeee eeeeeee eeeeeee eeeee eeee M8, eeeeeeee ee eee eeeeeeee ee eeeee MMM (88 eM). Mee eeeee eee eeeeee ee −88°M eee e eeeeeee ee eeeeeee eeeeeeeee MMMMe (88.8 eM, 88.8 e, 8.88 eee) eee MeMe8 (88.8 eM, 88.8 e, 8.88 eee) ee eeeee MMM (888 eM) eee eeeee eeee 8 e ee eeeeeeee eeeeee. Mee eeeeeeeeeee ee eee eeeeeee eeeeee eeeee eeeeee −88°M. Meeee eeeeeeee eee eeeeeeee, eeeeeeee eee eeeeeeeee eee 88 eee eeee eeeeeee, eeeeeeee ee eeeeeee ee ee. Meeeee 88–88 e eee eeeee ee eee eeee-eeeee eeeeeeeeee eeeeee eeee eeeeeee. Mee eeeeeeeeeee eee eeeeeee eee eee eeeeeee eee eeeeeeee eee 8 e ee eeeeeee eee eeeeeeeee MMMMe. Meeee eeeeeee ee ee, eee eeeeeeeee eee eeeeeeee eeee e M8 eeeeeee eee e eee eeeee. M 8.8 M eeee ee MeMe•MeMe ee Me8M (88 eM, 88 eeee) eee eeeee ee eee eeeeeeeeee eeeeeee eeee-eeeee eeeeeee. Meeeeeee eee eeeeeeeee eee 88 e; eee eeeeeee eeeeeeee e eeeeeeee eeee. Meeeeee (eee eeeee eeeeeee eee ee eeeeee eeeeeeeeee) eeeeeeeeee eee eeeeeee eee ee eeeeee eeeeee eee eeeeeee ee eee-eeee 8 M ee MMe (888 eM). Mee eeeeeee eeeee eee eeeeeeeee eeee eeeeeee (8 × 888 eM). Mee eeeeeeee eeeeeee eeeee eee eeeee (MeMM8) eee eee eeeeeeee eeee eeeeeee eeeee eeeeeee eeeeeeee. Meeeeeeeeeee eeeeeeee eeee ‌88‌ ee e eeeee eee; eeeee: 88.8–88.8 e (88–88%); ee 88°M/8 Meee.

References

Meeeeee Meeeeeeeeee

• 8.Meeeee-Meee, (8888) 88/8, 88.
• 8.Meeeee-Meee, (8888) 88/8, 88.