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4.4.22.2 Method 2: From Silyl Halides

DOI: 10.1055/sos-SD-004-00516

Pietruszka, J.Science of Synthesis, (20024475.

For the transformation of silyl chlorides or, less frequently, fluorides[‌37‌,‌38‌] and triflates,[‌38‌,‌39‌] lithium, sodium, potassium, and magnesium phosphides are used. Common solvents are diethyl ether, tetrahydrofuran, 1,2-dimethoxyethane, or higher boiling ethers.

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References


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