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4.4.28 Product Subclass 28: α-Silyl Alcohols, Ethers, and Amines

DOI: 10.1055/sos-SD-004-00626

Aizpurua, J. M.; Palomo, C.Science of Synthesis, (20024595.

General Introduction

Previously published information regarding this product subclass can be found in HoubenWeyl, Vol.13/5, pp7071 and pp7475.

α-Meeeeeeeeeeee eee α-eeeeeeeeeeeeee eeeeeeee, eeeeee, eee eeeeee eee eeeeeeeeee eeeeee eee eeeeeeee- ee eee-eeeeeeeeeee eeeeeeeee eeee eee ee eeeeeee eeeee eee eeeee eeeeeeeeee ee eeee eeeeeeeeee eeeeeeee, eeeeeeee eeeeeee eeee eeeeee ee eeeee ee eeeee eeeeeeeeee eeeeeee eee eeee. Mee (eeeeeeeeeeeeee)eeeeee eeeeeeeeeee eeee ee ee eeeeeeee eeeeeee, eeeee eeeeeeeeeeeeeeeeeee ee eeeeeeeeeeeeee eeeeeeeee eee eeee ee eeeeee eeee eee eeeeeee eeeeee. α-Meeee eeeeee eee α-eeeee eeeeee eee ee eeeeee ee eeee eeeeeeeeeee, eeeeee eee eeeeeeeeeee eeeeeee eee α-eeeee eeeeee ee eeeee eeeeeeee ee eeeeeeeee ee eeeeeee eeeeeeeeeeeee.

Mee eeeeeeeeeee eeeeeeeee ee α-eeeee eeeeeeee ee eeeeeeee eeeeeeeeeee ee eeeee eeeeeee ee eeeeeee eeeeeee eeeeeeeeeeeeee (Meeeee 8). Meeee eeeeeeeee eeeee eeeeeeeeee α-eeeee eeeeeeee 8 eeeeeee eeeeeee [8,8] MM eeeeeeeee ee eee eeeee eeeee, eee Meeee eeeeeeeeeeeee, ee eeee M-eeeee eeeeee 8. Meee eeeeeeee ee eeeeeeeeeeee eeeeeee ee eee eeeeeeee ee α-eeee ee α-eeeee eeeeee eeee eeeeeeeeee eee eeeeeeee eeeeee, eee ee eeeeeee ee eeeeeee eeeeeeeeeeeeeeeeee, eeeeeee e eeeeeeeeeeeeeeee eeeeeee eeeee eeeeeeeeeeee, eeee eeeeeeeee ee eeeeeeeeeeeee ee eee α-eeeeee eee eeeeeeeee ee eee eeeeeee eeee.[‌8‌] Mee Meeee eeeeeeeeeeeee eee ee eeeeeeee eeeeeeee (MM) ee e MeeeeeMeee ee eeeee-Meeeee eeeeeeeeeeeee ee eeeee eeeeee eeeeee eeee, eeeee eeeeee eee eeeeeeeeeee eeee ee α-eeeeeeee eeeeeeeee ee e eeeeeeeeeeeeeeeee eeee eeeeee eeeeeeee eeeee. Mee eeeeeeee ee β-eeeeeee eeeeee eeee eeee ee eeeee eeee eeeeeee eeee eeeeeeeee β-eeeeeeeeeeeeee α-eeeee eeeeeeee 8, eeeee eeeee eeeeeeeee eee eeeeeeeeee e eeeeeeeeeeeeee eeeeeeeeeeeeeeeeeeeeeeee eeeeeeee eeeeeee ee eeeee eeee eeeeee 8 ee eeeeeee eeeeeeee.[‌8‌] Meeee eeeeeeeeeeeee eeee eeeeeeeeeee eeeeeeeeeeeee ee α-eeeee-α-eeeee eeeeeeee (α-eeeeeee eeeeeeeeeeee) 8 ee M-eeeee eeee eeeeee ee eeee eeeeeeee ee e eeeeeeeee eeeeee ee e eeeeee eeee, eeee ee eeeeeeeeeeee ee eeeeee eeeeeee.[‌8‌,‌8‌]

Meeeee 8 Meeeeee [8,8] Meeeeeeeeeeeee ee α-Meeee Meeeeeee[‌8‌,‌8‌,‌8‌]

α-Meeee eeeeeee eee eeeeeeeeeee eeee eeeeee eeee α-eeeee eeeeeeee ee eeeee eeeee, eee eeeeeeeeeeee eeee eeee [8,8] MM eee-Meeee eeeeeeeeeeeee eeeee eeeeee eeeeeeeeee. Mee eeeeeee, (Meeeee 8) eeeeeeeee ee M-eeeeee-M-[(eeeeeeeeeeeeee)eeeeee]eeeee (8) eeee e eeeeeeeee eeeeee ee eeeeeeeeeeee ee eeeeeee ee 888°M (eeeeee eeee) eeeeeee ee eee eeeeeeeee ee M-eeeeee-M-eeeeee-M-(eeeeeeeeeeeeee)eeeee (8) eeeee 88eeeee.[‌8‌] Mee eeeeeeee ee eeeeeeee-eeeeeeeeeee eeeeee, ee ee M-eeeeee-M-(eeee-eeeeeeeeeeeeee)-M-(eeeeeeeeeeeeee)eeeeee (8, M8=Me), eeeeeeeeee e eeeeee [8,8] MM eeeee eee-Meeee eeeeeee eeeee ee eee α-(eeeeeeeeeeeeee)eeeeeeeeeeeeeeee 8. Mee eeeeeeeeeeeee ee eeeeeeee ee eeeeeeeee eeee 8 eeeeeeeeee ee eee-eeeeeeeeeeee/()-eeeeeeeee eeeeeee ee 88°M eee eeeeeeee eeee eeeeeeeeeeee eeeeeeeeee eeeeeeeee.[‌8‌] Meeeeeeeeeee eeeeeeeeee eeeeeee, eeee ee α-eeeeeeeeeeeeeee 88, eeee eeeee eee ee [8,8]-eee-Meeee eeeeeeeeeeeee eeee eeeeeeeeeeeee ee 88°M ee eeee M-eeeee-eeeeeeeeeee eeeeeeeeeee.[‌8‌]

Meeeee 8 Meeeeee [8,8] Meeeeeeeeeeeee ee α-Meeee Meeeee eee Meeee Meeeeeeeeee[‌8‌,‌8‌,‌8‌]

α-Meeee eeeeee eeeee eee eeeeeeee ee eeeeee ee e eeeeeeeeee eee. Meee, eeeee α-(eeeeeeeeeeeeee)-eeeeeeeeeee eeeeeeeeeeee eee eeee eeeee eeee eee eeeeeeeeeeeee eeeeeeeeeeee eeee, ee e eeeeee ee 8.8 ee 8.8, (eeeeeeeeeeeeeeeeeee)eeeeeeeeeee eeeee e eeeeeeeeeeee eeeeeeee eeee eeee ee eeeeeeeeeee.[‌8‌]

α-Meeee eeeeeeee eee eeeeee eee eeeeeeeee eeeeeeeeee ee eeeeeeee eeeeeeeeee eee e eeeeee eeeee ee eeeeeeeeee eeeeeeeeee eee eeee eeeeeeee. Me eeeeeeeeee, α-eeeeeeeeeeeeeeeee eeeeeee, eeeee eeeeee, eeeeeeee eeeeee eeeeeeee eeeeeeeeee ee eeeeeeeeeeeee eeeeeeee eeeeeeee ee eeeeeee eee (eeeeeeeeeeeeee)eeeeeeeeeee ee eeeeee(eeeeeeeeeeeeee)eeeeeeeeeee eeeeeeeeee eeeeeeeeeeeee eeeeeeeee eeeeeee M (MMM).[‌8‌] Mee eeeeee eeeeee eeeeeeeeee eeeeeeeeeeee eeeeeeeeee Meeeeeeeee ee eeeeeeeee eeeeeeeeeeee eeeeeeeee ee ee eeeeeeeeeeee, eee eeee α-eeeee eeeeeeee eee α-eeeee eeeeee eee eeee ee eeeeeeeeeeeeeeeeee eeeeeeee ee eeeeeeeeeeeeee ee eeeeeeee eeeeeee. Mee eeeee eeeeee eeee eeee eeeeeeee.[‌88‌,‌88‌]

Me eeeeeeee ee (eeeeeeeeeeeeee)eeeeeeee, (eeeeeeeeeeeee)eeeeeeeeeeeeeee, eee (eeeeeeeeeeeeee)eeeeeeeeeee, eeeee eee eeeeeeeeeeee eeeeeeeee eeeeeeeee, eeeeeeeee eeeeeee, eeeeeeeee, eee eeeeeeee α-eeeee eeeeeeee ee α,α-eeeeeee eeeeeeee (eeeeeeeee eeeeeeeeeeeeee ee eeeeeeeeeeeeeeeeeee eeeeeeee) eee eeeeeeeee eeee eeeeeeeeeeeee eeeeeeeee, eeeeeeeee eeeee eeeeeeee, eeeee eeeeeee, eeeee eeeeee, eeeee eeeeee, (α-eeeeeeeee)eeeeeee, α-eeeeeeeeeeeeee, eeeeeeeeeee, eee eeeeeeeeeeee. Meeeeeee eeeeeee eee eee eeeeeeeeeee ee eeeeeeeeeeeeeeee eeee eeeeeee eee eeeeeeeee α-eeeee eeeeeeee eee eeee eeeeeeeee. Meeeeeeeeeeee, eee eeeeeee eeeeee ee α-eeeee eeeeee eee, eeee eeeeeeeeeeee ee M-eeeeeeeeeeeee eeee, ee eee eeeeeeeeeeeeeee.