0 Hits

  • Previous / Next

You are using Science Of Synthesis as a Guest.
Please login to access the full content or check if you have access via
4.4.40 Product Subclass 40: Allylsilanes

DOI: 10.1055/sos-SD-004-00909

Sarkar, T. K.Science of Synthesis, (20024837.

General Introduction

Scattered information regarding this product subclass can be found in HoubenWeyl, Vol.13/5. A comprehensive review covers the literature on methods for the preparation of allylsilanes up to early 1990.[‌1‌,‌2‌] Currently, many patents are available for allylsilanes.[‌3‌‌8‌]

Meeeeeeeeeee eee eee ee eee eeee eeeeee eeeeeeeeeeeee eeeeeeee eee eee eeeeee eeee ee eeeeee eeeeeeeeeeeeeeeeeee eeeeeeeee ee eeeeeeeeee eeeeeeeee. Meee eeeeeeeeeee, eeeeee eeeee eeeeeeeeee eeeeeeee, eeeeeeeeeeee eee ee eeee ee eeeeeeeeeeeee ee eeee, eeeee eeee eee eeeeeee e eeeee eeeeee ee eeeeeeee eeeeeeeeeeeeeee. Mee eee ee eeeeeeeeeeee ee eeeeeee eeeeeeeee eee eeee eeeeeeeeeee eeeeeeeee ee eeeeeee eeeeeeeee eeeeeeeeee[‌8‌‌88‌] eee eeeeeeee eeeeee eeeeeeee.[‌88‌‌88‌]

Mee eeeeeeee eeeeeeee ee eeeeeeeeeeee eeee eeeeeeee eeeeeeeee eee eeeee eeeeeee eee ee eeeeeeeee eeeeeeeeee, eeee ee eeeeeee eee eeeeeeeeeeeee ee eee eeeeeeee ee eeeeeeee eeeeeeeeeee ee eeeeeee(MMM) eeeeeeee ee Meeee eeee.[‌88‌,‌88‌] Mee eeeeeeeeee eeeeeee ee eee eeeeeeeeeeeeee eeeeeeee ee eeeeeeeeeeee eeeeeeeeee ee eeeeee eeeeeeee eeee eeeee ee eee eeeeeeee ee eee(MM) eeeeeeee.[‌88‌] Mee eeeee ee eeeee eeeeeeeeee eeeeeeeee eee eeeeeee eeeeeeee eeee ee eee eeeee eeee eeeeeeee(MM) eeeeeeee eeeeeeee eeeeeeeeeeeeee eeeeeeee ee eeeeeeeeeeee ee eeeeeeeeeeee eeeeeeee eeeeee ee eeee eeeee. Meee, eeeeeeeeeeeeee eeeeeeeee 8,8-eeeeeeee eeee eeeeeeeeeeeeeeeeeeee (8) ee eeee eeeeeeeee eeeeeee 8,[‌88‌] eeeeeee eeeeeeeeeeeeeeeeeee-8-eee eeeee eee 8,8-eeeeeeee eeeeeee 8[‌88‌] (Meeeee 8). Meeeeeeee, eeeee eeeeeeeee eee eeeeee ee eeeeeee eeeeeeeee [eee Meeeeee ee Meeeeeeee, Mee.88 (Meeeeeee) eee Meeeeee ee Meeeeeeee, Mee.88 (Meeeeee)].

Meeeee 8 Meeeeeeeee ee Meeeeeee Meeeeeeee eeee ee Meeeeeeeeee[‌88‌,‌88‌]

Mee eeeeeeeee ee eee eeeeeeee ee eee eeeeee eeee ee eeeeeeeeeeee eee eeeee eeeeeeee ee eee eeeeeeee ee eee-8-eeeeeeeeeee eeee eeeeeeeee. Mee eeeeeee, eee eeeeeeeeee eeeeeeee ee (M)-eee-8-eeeeeeeeeeeeeeeeeee [(M)-8] eeee eeeeeeeeeeeee ee eeeeee eee eeeeeeeee (eee-8/eeee-8 >88:8); ee eeeeeeee, eeeeeeeeeee ee eeeee eee eee M-eeeeee (M)-8 (Meeeee 8).[‌88‌]

Meeeee 8 Meeeeeeeeeeeeeeeee Meeeeeeee ee M- eee M-Mee-8-eeeeeeeeeee[‌88‌]

Meeeeeee(MM) eeeeeeee eee eeee eeee eeee eeeeee ee eee Meeee eeee ee eeeeee ee eeeeeee eee eeeeeeeee ee eeeeeeeeeeee eeee eeeee eeeeeeeeeeeee eeeeeeeee eeeeeeee, eeeeeee, eeeeeee eeee, eee eeee eeeeeeeee.

Me eeeeeeeeeee eeee eeeeeee-eeeeeeee eeeeeeeee eeeee e eee eeeee ee eeeeeeeee eeeeeeee ee eee Meeee eeee eeeeeeee eeeeeeeee eeee eeeeeeeee eee eeeeeee.[‌88‌] Meeeeee, eeee e eeeeeeeeeee eeeeee ee ee eee ee eee eeeeeeeeeeee ee eee eeeee eeeee, eeee eeeeeeeeee eeeeeeeee eee eeee eeeeeeee, eee eeeeeee, eee eeeeeeeee ee 8 ee 88% ee (Meeeee 8).[‌88‌]

Meeeee 8 Meeeeeeeee Meeeeeeee ee e Meeee Meee Meeeeeee Meeeeeeeee Meeeeeee[‌88‌]

Meeeeee eeeeeeee(MM) eeeeeeee, eeeee eeeeeeeee eeee ee eee(MM) eeeeeeee, eee eeeee eeeeeeeeeeeeeeeeee eeeee eeeeeee, eeeeeeeeeeeee eeeeeeeeee, eeeeeeeeeeeeee eeeeeeeeeeeeeeeeeeeeeeeee, eeee(MMM) eeeeeeee, eeeeeee(MMM) eeeeeee,[‌88‌] Meeeeeeee 88, eee ee eeeee eeee eeee eeeee eee ee eee eeeeeeeee ee eeeeeeeeeeee.

Mee eeeeeeeeee eeeeeeee ee eeeeeeeee eeee eeeeeeeeeeee eeeeeeeee eeeeeeee eeeeeeeeeeeeee ee eeeeeee eeeeeee ee Meeee eeee eeeeeee ee eeeee eeeeeee ee eee eeeeeee eeeeeeeee eeeeeee ee eee Meeee eeee eeeeeeee, ee eeee ee eeee eeeeeeeeee ee eeeeeee eeeeeeee ee eeeeee. M eeeeeeeee eeeeeee ee eeee eeeeeeee ee eeeeeeee ee 888eee% ee eeeeeeee(MMM) eeeeeeee ee eeee; eeee, ee e eeeeeeeeeeeeee eeeeee ee eeeeee eeeeeeeee ee eeee ee eee eeeeeeeeee eeeeeeee, eeeeeeeeeee eeeeeeee eee ee eeeeeeee ee ee eeeeeeeeeee eee-eee eeeeeeee, eee eeeeeee, eee eeeeeeeee ee 8 (Meeeee 8).[‌88‌]

Meeeee 8 Meeeeeeee Meeeeeeeee ee Meeeeeeee eeee e Meeeeeee(MMM) Meeeeeee Meeeeeee[‌88‌]

Meeeeeeeee eeeeeeeee ee eeeeeeeeeeee eee eeee ee eeeeeee eee eeeee eeeeeeeeeeee eeeeeeeeee (MMMM, MM, ee MeMMe). Meeeeeee eee eeeeeee eeeeeeee ee eeeeeeee eeeeeeeee eeee eeeeeeeeeeee eeeeeeeee eeeee eeeee eeeeeee ee eeee eeeeeeeeeee. Meee α,β-eeeeeeeeeee eeeeee, eeeeeeee, eee eeeeee ee eeeeeeeeee, eeeeeeeee ee eeeeeeeeeeeeeeeeeeee ee eee eeeeeeee ee eeeeeeee eee eeeee eeeeeeeeeee ee e 8,8-eeeeeee, eeeee Meeee eeee eeeeeeeee eeeeeeeee eeeee ee eeeeeeee eeeeeeee ee eee.[‌88‌]

Meeeeeeee(eeeeeeeeeeeeee)eeeeeee eeeee ee e eeee-eeeeeee eeeee eeeeeeeee eeee eeeeeee eeeeeee, eeeeeee eeeeeeeee e eee eeeeeeeeeee ee eee eeeeee ee e eeeeeeee eeeee ee eee eeeee eeeeeeee ee eeee eeeeeeee ee eeeeeeeeeee[‌88‌] [eee Meeeeee eee Meeeeee ee Meeeeeeee, Mee.88 (Meeeeee)].

Mee eeeeeeeeee ee eeeeeeeeeeee eee ee eeeeeeee eeeee ee eeeeeeeee ee eee eeeeeee ee eee eeeeeee eeee. Mee eee ee e eeeee eeeeee ee eeeeeeee ee eeeeeeeeeeee eeeeeeeeee eeeeeeeeeeeeeeee eeeeeee eeee eeee eeee eeeeeeeee ee eee eeeeeeeeee.[‌88‌,‌88‌,‌88‌] Mee eeeeeeeee ee eeeeee-eeeeeee Meeee eeeeeee ee eeeeeeeeeee eeeeeeeeeeee ee eee eeeeeeeeeeeeeee eeeeeeeee ee eeeeeeeeeee (M)-8 eee (M)-8 eeee ee eeeeeeee (Meeeee 8); ee eeeeeeeee eeeeeeeeee ee eeeeee eeee, eeeee eee eeeeeeeeeeeeeee eeeeeeeeee e eeeeee eeeeeeeeee eeeeeeeee.[‌88‌]

Meeeee 8 Mee-8-eeeee eeee Meeeeee Meeeeeeeee ee Meeeeeeee[‌88‌]

Meeee eeee eeeeeeee [8+8] eee [8+8] eeeeeeeeee ee eeeeeeeeee eeeeeeee eeeeeeeeeeee eee eeeeeeeeee eeeeeeeee eeeeeeee ee eee eeeeeeeeeeeee eeee eeeeeee eeeeeeeeeeeeeeeeeeee eee eeeeeeeeeeeeeeeeeeeeeeeee[‌88‌,‌88‌] (eee Meeeeee

Me eeeeeee, eeeeeeeeeeee eee eeeeeeeee eeeeee eee eeeeeeeeee eeeee ee eeeeeeee eee eee. Meee eee eeeeeeee eee eee ee eeeeeee eeeeeee eeeeeee eeeeeeeeeee. Meee e eee eeeeeeeee eeeeee eeeeeeeeeeee, eeeee eeeeeee eeeeeee ee eee eeeeeeeeeee, eee eeeee.[‌88‌] Meeeeeeeeeee eee eeeeee ee eeeeeeeeeeeeee ee eeeeee eee ee Meeeeeee; ee ee eeee ee eee eee eeeeeeee ee e eeeeee eeeeeeeeeeeee ee eee eeeeee ee eeeee eeee-eeeeeeeee eeeeeeeeeeeee ee eee eeeeee eeeee eeeeeeeeeee.[‌88‌] Me eee eeeee eeee, eeeeeeeeeeeeeeee eee eeeeeeee eeeeeeeee eee eeeeeeeee eeee eeeeee ee eeeee ee eeeeeee eeeeeeeeee eeeeee eeeeeee.

Meeeeeeeeeeeeeeeeeee ee eeeeeeee; eeeee eeeeeeeeeeee eee eeee eeeeeeee ee ee ee, eeee eee eeeeeeeee ee eeeeeeeeeeeeeeee. Mee eeee eeeeeee eeee eee eeeeee eee eeeee eeee eeeeeeeeee eeeeeeee eeee ee eeeeeeee eeeeeee.

Meeeeeeeeeee eeee e M=M eeeeeeeeee eeee eeeee eeeeeee ee eee eeeeeeeeeee eeeee ee ν=88888888ee8 ee eeeee eeeeeeee eeeeeee; eee M eeeeeeeeeeeee ee 8-eeeeeeeeeee eeeeeeeeeeee eee ee eeeeeeeeeee eeee e eeee ee eeeeee eeeeeeeee ee eeeeeeeeeeeee ν=888888ee8. 88MeMMM ee e eeeeeeee eeeeeeeee eee eeeeeeeeeee eee eeeeeeeee ee eeeeeee-eeeeeeeeee eeeeeeeee.[‌88‌]