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4.4.40.7 Method 7: From α-Heteroalkenes by Transition-Metal-Catalyzed Cross Coupling

DOI: 10.1055/sos-SD-004-00909

Sarkar, T. K.Science of Synthesis, (20024846.

Allylsilanes are available from α-heteroatom-substituted alkenes, such as vinyl halides,[‌80‌‌85‌] enol phosphates,[‌86‌‌88‌] vinyl triflates,[‌89‌,‌90‌] and other vinylic compounds,[‌91‌‌93‌] by transition-metal-catalyzed cross coupling of silyl organometallics.

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