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4.4.40.21 Method 21: Formation of Bis(allylsilanes) from 1,3-Dienes

DOI: 10.1055/sos-SD-004-00909

Sarkar, T. K.Science of Synthesis, (20024862.

Bis(allylsilanes) 80 have been prepared with complete control of regio- and stereoselectivity from 1,3-dienes by a palladium-catalyzed dimerizationdisilylation reaction (Scheme 36).[‌141‌] It should be noted that this procedure yields exclusively E-1,4 head-to-head dimeric allylsilanes from 2-substituted 1,3-dienes.[‌141‌]

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