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5.2.29.7.1 Variation 1: With Palladium

DOI: 10.1055/sos-SD-005-00593

Young, D.Science of Synthesis, (20035615.

The popular palladium-catalyzed substitution reactions of organostannanes (Scheme 13)[‌23‌] involve electrophilic cleavage of the SnC bond by a palladium complex, but there are only a few examples of the use of alkylstannanes, which have the slowest transfer rate in this reaction and are the least useful substrate from a synthetic perspective.[‌22‌]

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