Science of Synthesis

Albrecht, K.; Kaufmann, D. E., Science of Synthesis, (2005) 6, 701.

Zirconocene-mediated coupling of C—C bonds is an established procedure in organic synthesis,[‌41‌] and can also be applied to the preparation of organoboronates.[‌42‌,‌43‌] Starting from alkynylboronates, it allows the direct access of dienyldiboronates which are otherwise difficult to obtain, and are valuable building blocks for the synthesis of substituted polyene systems.

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References