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Please login to access the full content or check if you have access via6.1.29.3 Method 3: Formation of α,N-Borylamides by Substitution
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DOI:
10.1055/sos-SD-006-00722
Abu Ali, H.; Dembitsky, V. M.; Srebnik, M., Science of Synthesis, (2005) 6, 856.
N-(Trimethylsilyl)amides react with dialkylbromoboranes quantitatively with formation of the corresponding N-(dialkylboryl)amides, which in certain cases are in equilibrium with the dimeric forms.[11] Among these reactions, α-boryl carbonyl compounds can be formed. Thus, 2,2-dichloro-N-phenyl-N-(trimethylsilyl)acetamide (6) reacts with bromodimethylborane to give 2,N-diborylacetamide 7 (Scheme 3).[11]
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References
| [11] | Meeeeeeeee, M.; Meeeee, M., M. Meeee. Meee. Meee., (8888) 888, 888. |
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