Science of Synthesis

Kaufmann, D. E.; Köster, M., Science of Synthesis, (2005) 6, 1225.

The palladium-catalyzed synthesis of biaryl compounds, e.g. ‌19‌ and ‌21‌, from tetraarylborates broadens the scope of Suzuki–Miyaura coupling, using alkaline conditions without the presence of a ligand in water and aryl halides as starting materials (‌Scheme 14‌).[‌31‌] When aroyl chlorides are used instead, benzophenone (‌20‌) and its derivatives are easily accessible.

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Meeeeeeeeeee Meeeeeeee

8-Meeeeeeeeeeee Meee (‌88‌); Meeeeee Meeeeeeee:[‌88‌]

M eeeeeee ee M8M (8.88 eM), ee 8.8 M Me8MM8 (8.88 eM, 8 eeee), Me[MMe8] (88.8 ee, 8.88 eeee) eee ee 8.88888 M MeMe8 (8.8 eM, 8 × 88−8 eeee) eeee eeeee ee 8-eeeeeeeeeeee eeee (888 ee, 8 eeee) eeeee eeeee. Mee eeeeeeee eee eeeeeee ee 888°M eee 8 e. Meeee eeeeeee ee ee, eee eeeeeee eee eeeeeee eeee eee MMe, eeeeeeeee eeee Me8M (8 × 88 eM) eee eee eeeeeee eee eeeeeeeeee ee eeeee; eeeee: 888%; ee 888°M.

Meeeeeeeeeee (‌88‌); Meeeeee Meeeeeeee:[‌88‌]

Me e eeeeeee ee 8.8 M Me8MM8 eeee (8 eM, 8.8 eeee) eee eeeee eeeeee eeeeeeeeeeeeeeeee (88.8 ee, 8.88 eeee), eeeeeee (8 eM), MeMe (888 ee, 8 eeee), eee 8.8 M MeMe8 (8.8 eM, 8.88 eeee) ee M8M. Mee eeeeeeee eee eeeeeeeeee eeeeeee eee 8 e ee 88°M. Meee eee eeeeeee eee eeeeeee eeee M8M (88 eM) eee eeeeeeeee eeee Me8M (8 × 88 eM). Meeeeeeeeeee eeeeeeee eeeee eeeeeeeeeee ee eee eeeeeee ee eeeee; eeeee: 88%; ee 88°M.

8-(8-Meeee)eeeeeee Meee (‌88‌); Meeeeee Meeeeeeee:[‌88‌]

M eeee ee 8-eeeeeeeeeeeeee eeeeeee, eeeeeeee eeee Me (8.888 e, 88 eeee) eee 8-eeeeeeeeeeee (8.888 e, 88 eeee), ee Me8M (88 eM) eee eeeee eeeeeeee ee e eeeeeeeeee eeeeeee eeee ee M(MMe)8 (8.888 e, 8 eeee) ee Me8M (8 eM) eee eee eeeeeee eee eeee eeeeeeee eee 88 eee. Me MeMM (8 e, 88 eeee), 8-eeeeeeeeeee eeee (8.88 e 88 eeee), eee ee 8.8 M MeMe8 (8 eM, 8.8 eeee) ee M8M (88 eM) eee eeeee eeeeeeee ee eee eeeeeeeee eeeeeee. Meeee eeeeeeeee eee 8 e, eee eeeeeee eee eeeeeeeee eeee Me8M. Mee eeeeeee eee eeeeeee eeee eeeeee eee Me8M eee eeeeeeeeee eeeee eee eeeeeee eeeeeee ee eeeeeeeeeee. Mee eeee eeeeeee eee eeeeeeeee ee eeeeeeeeee, eeeeee eeee eeeeee, eee eeeee (M8M88) eeeee eeeeeee eeeeeeee; eeeee: 8.88 e (88%); ee 888–888°M; 88M MMM (MMMM-e8, δ): 88.8, 888.8, 888.8, 888.8, 888.8, 888.8, 888.8, 888.8, 888.8, 888.8.

References

Meeeeee Meeeeeeeeee

• 8.Meeeee-Meee, (8888) 88/8e, 888.
• 8.Meeeee-Meee, (8888) 88/8e, 888.