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Ooi, T.; Maruoka, K., Science of Synthesis, (2004) 7, 146.
Aluminum alkoxides are very effective for epoxide ring-opening reactions. α-Pinene oxide rearranges to pinocarvenol in the presence of 1 mol% of aluminum triisopropoxide at 100–120°C for 1 hour, while pinanone is obtained upon conducting the reaction with 5 mol% of aluminum triisopropoxide at 140–170°C for 2 hours (Scheme 35).[42]
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References
| [42] | Meeeeee, M., Meeeeeeee, (8888), 888. |
| [43] | Meeeeee, M.; Meeeee, M.; Meeee, M., Meeeeeeee, (8888), 888. |
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