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DOI:
10.1055/sos-SD-007-00142
Ooi, T.; Maruoka, K., Science of Synthesis, (2004) 7, 208.
Nonenzymic heterolysis of allyl phosphate esters with concurrent generation of a new S—C bond can be realized by the reaction with dimethylaluminum alkanethiolates.[33] For instance, treatment of a geranyl or neryl phosphate ester in hexane with dimethylaluminum alkanethiolates results in the formation of sulfides in a regio- and stereospecific manner (Scheme 25).
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References
| [33] | Meeeeeee, M.; Meeeeeeee, M.; Meeeee, M.; Meeeeeee, M.; Meeeee, M., M. Me. Meee. Mee., (8888) 88, 8888. |
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