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7.6.13.10 Method 10: Reactions Involving Magnesium Methoxide

DOI: 10.1055/sos-SD-007-00630

Shimizu, M.Science of Synthesis, (20047650.

Methylmagnesium carbonate (5) is readily generated by the reaction of magnesium methoxide (2) with carbon dioxide in dimethylformamide (see Section 7.6.13.5).[‌14‌,‌30‌] This reagent is useful for the carboxylation of a variety of anions (Scheme 10).

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