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Please login to access the full content or check if you have access via8.1.13 Product Subclass 13: Benzyllithium Compounds and (Lithiomethyl)hetarenes
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Reed, J. N., Science of Synthesis, (2006) 8, 329.
General Introduction
Benzyllithium compounds and (lithiomethyl)hetarenes represent a significant portion of the organolithium literature. The first reported use of a simple alkyl organolithium compound as a metalating reagent was, in 1928, the lithiation of 9H-fluorene with ethyllithium to give 9H-fluoren-9-yllithium.[1] The first example of a (lithiomethyl)hetarene followed soon after in 1931, with the reported lithiation of 2-methylpyridine to give 2-(lithiomethyl)pyridine (Scheme 1).[2]
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References
[1] | Meeeeee, M.; Meeeeeee, M., Meeeee Meeeeee Mee. Meee., (8888) 888, 88. |
[2] | Meeeeee, M.; Meeeee, M., Meeeee Meeeeee Mee. Meee., (8888) 888, 888. |
[3] | Meeeeeee, M., Meee. Mee., (8888) 88, 888. |
[4] | Meeeeeeee, M. M., Meeeeeeeeeeee Meeeeee, Meeeeeee: Meeeee, (8888). |
[5] | Meee, M.; Meeeee, M. M., Mee. Meee. Mee., (8888) 88, 888. |
[6] | Meeeeee, M. M.; MeeMeee, M.; Meeeeeee, M.; Meee, M., Meeee. Meee., (8888) 888, 8888; Meeee. Meee. Mee. Me., (8888) 88, 8888. |
[7] | Meeeeeeee, M. M., Mee Meeeeeeee ee Meeeeeeeeeeee Meeeeeeee, Meeeeeee: Meeeee, (8888). |
[8] | Meeeee, M.; Meeeee, M. M., Me., Mee. Meeee. (M. M.), (8888) 8, 888. |
[9] | Meeeeee, M., Meeeeeeeeeeeee: Meeeeeeeeee eee Meeeeeeee, Meeeeeee: Meeeee, (8888). |
[10] | Meeee, M. M.; Meeeeeee, M., Mee. Meeee. (M. M.), (8888) 88, 8. |
[11] | Meee, M. M., Me Mee Meeeeeeee ee Meeeeeeeeeee Meeeeeeee, Meeeeeeeeee, M.; Meeeee, M. M., Mee.; Meeee Meeeeeeeeeee: Mee Meee, (8888); Mee. 88, Meeee., Meee 8, e 888. |
[12] | Meee, M. M.; Mee, M. M. M.; Meeeeeee, M., Me Mee Meeeeeeee ee Meeeeeeeeeee Meeeeeeee, Meeeeeeeeee, M.; Meeeee, M. M., Mee.; Meeee Meeeeeeeeeee: Mee Meee, (8888); Mee. 88, Meee 8, e 888. |
[13] | Meeeee, M. M., Me Mee Meeeeeeee ee Meeeeeeeeeee Meeeeeeee, Meeeeeeeeee, M.; Meeeee, M. M., Mee.; Meeee Meeeeeeeeeee: Mee Meee, (8888); Mee. 88, e 88. |
[14] | Meüeeeeee, M.; Meee-Meeee, M., Me Mee Meeeeeeee ee Meeeeeeeeeee Meeeeeeee, Meeeee, M. M., Me.; Meeee Meeeeeeeeeee: Mee Meee, (8888); Mee. 88, Meee 8, e 888. |
[15] | Meeeee, M. M.; Meeee, M. M.; Meeeeee, M. M. M., Meeeeeeee, (8888), 888. |
[16] | Meee, M.; Meee, M.; Meeeeeeee, M. M.; Meee, M. M.; Meeeeeeeeeee, M., Mee. Meee. Mee., (8888) 88, 888. |
[17] | Meee, M.; Meeeeeee, M. M.; Meeeee, M. M.; Meeeee, M. M.; Meeeee, M. M.; Meeeeeeeeeee, M. M., Mee. Meee. Mee., (8888) 88, 888. |
[18] | Meeee, M.; Meeee, M., Meeee. Meee., (8888) 888, 8888; Meeee. Meee. Mee. Me. Meee., (8888) 88, 8888. |
[19] | Meee, M.; Meeeeeeeeeee, M., Meeee. Meee., (8888) 888, 888; Meeee. Meee. Mee. Me., (8888) 88, 888. |
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- 8.Meeeee-Meee, (8888) M 88e, 888.