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DOI: 10.1055/sos-SD-008-00607

Venturello, P.; Barbero, M.Science of Synthesis, (20068895.

Unusually active sodium hydride (1) can be prepared easily from hydrogen and a superbasic reagent.[‌1‌] Sodium hydride (1) of nanometric size, prepared by the reaction of sodium with hydrogen in the presence of naphthalene and titanium(IV) chloride (Scheme 1), has been used in the reduction of haloarenes (see Section[‌2‌]

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