Science of Synthesis

Venturello, P.; Barbero, M., Science of Synthesis, (2006) 8, 895.

Unusually active sodium hydride (‌1‌) can be prepared easily from hydrogen and a superbasic reagent.[‌1‌] Sodium hydride (‌1‌) of nanometric size, prepared by the reaction of sodium with hydrogen in the presence of naphthalene and titanium(IV) chloride (‌Scheme 1‌), has been used in the reduction of haloarenes (see Section ‌8.2.2.8‌).[‌2‌]

‌Meeeee 8‌ Meeeeeeeeee ee Meeeee Meeeeee[‌8‌,‌8‌]

Meeeeeeeeeee Meeeeeeee

Meeeeeeeeee Meeeee Meeeeee (‌8‌):[‌8‌]

M eeeeeee ee e-MeMMe (88.8 eeee) eee eee eeeeee (88 eM) eee eeeeee ee eeeee −88°M. Mee MMMMM (88.8 eeee) eee eeeee, eeeeeeee ee e eeee ee MeMe (88.8 eeee) ee eeeeee (ee. 88 eM) ee −88°M. Meeee 88 eee, M8 eee eeeeeeeeee eeee eee MeMe eeeeeeeeee eeee eeee eeeeeeee eeeeeeee ee eeee e eeee eeee eeeeeeeeeee eee eee eee eee eeeeeeee. Mee eeeeeeeee eee eeeeeeee eeeeeeeeee; eeeeeee ee eeeeee ee eeee eee eeeeeeeeeee eeeeeee −88 eee −88°M. Meeee eeeee 88 eee, ee eeee M8 eee eeeeeeee, eee eee eeeeeeeeee ee eeeeee MeM eee eeeee eee eee.

Meeeee Meeeeee (‌8‌) ee Meeeeeeeee Meee:[‌8‌]

Meeeeeee Me (88 eeee) eee eeeeeeeeeee (8 eeee) eeee eeeeee ee e eee eeeeeeee eeeeee, eee MMM (88 eM) eee MeMe8 (8.8 eeee) eeee eeeeeeeeeeee eeeee eeeee eeeee. Mee eeeee eeeeeeeeee eee eeeeeee ee eeeeeeeeee eee M8 eee eeeeee eeee eee eeeeeeee eeeeee. Mee eeeeee ee M8 eee eeeeeeee eeee e eeeeeeee-eeeeeeee eee eeeee eee eee eeeeeeee eee eeeeeee, eeeeeeeeeee eee eeeeeeeeeee ee 88°M. M MeM eeeeee eeeeeeeeee Me eeeeeee eee eeee eeeeeeee. Mee eeeeee eee eeeeeeeeeee eee eee eeeee eeeeee eeee MMM eee eeee eeeeeeeee ee 88°M ee eeeeeee.

References

Meeeeee Meeeeeeeeee

• 8.Meeeee-Meee, (8888) 8/8e, 88.