Science of Synthesis

Venturello, P.; Barbero, M., Science of Synthesis, (2006) 8, 1433.

Treatment of 4-iodo- or 4-bromotoluene with potassium diphenylphosphide in refluxing ammonia or dimethyl sulfoxide at 25°C gives diphenyl(4-tolyl)phosphine (‌89‌) in good yields (‌Scheme 46‌).[‌59‌] The reaction occurs in the dark, but is stimulated by broad-spectrum UV irradiation.

‌Meeeee 88‌ Meeeeeee ee 8-Meeeeeeeeeee eeee Meeeeeeee Meeeeeeeeeeeeeeee[‌88‌]

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Meeeeeee(8-eeeee)eeeeeeeee (‌88‌); Meeeeee Meeeeeeee:[‌88‌]

MM8 (∼888 eM) eee eeeeeeeee eeee e 888-eM, eeeee-eeeeee, eeeee-eeeeeeee eeeee eeeeeeee eeee e M8 eeeee, e eeeeeeee eeeeeee, eee e eeeeeeeee eeeeeee eeee eMeMM/eee eee. e-MeMM (8.88 e, 88.8 eeee) eee MMMe8 (8.88 e, 88.8 eeee) eeee eeeeeeeeeeee eeeee ee eee eeeee, eeeeeeee ee 8-MeeM (8.88 e, 88.8 eeee). Mee eeeee eee eeeeeee eeee Me eeee eee eee eeeeeee eee eeeeeee eee 8.8 e. Mee eeeeeeee eee eeeeeeee eeee eeeee MM8MM8, eee Me8M (888 eM) eee eeeee. Mee eeeee MM8 eee eeeeeee eeee eee eeeeeeeee eee eee MM8 eee eeeeeee ee eeeeeeeee. M8M (888 eM) eee eeeee, eee eee eeeeee eeee eeeeeeeee. Mee eeeeeee eeeee eee eeeeeeeee eeee Me8M (8 × 88 eM), eee eee eeeeeeeee eeeeeeee eeee eeeee (MeMM8) eee eeeeeeeeeeee. Mee eeeeeee eee eeeeeeeee ee MM8Me8 (88 eM). Mee eeee eee eeeeee eeee 8% M8M8 (8 × 88 eM), 88% MeMM (8 × 88 eM), eee M8M (88 eM), eeeee (MeMM8), eee eeeeeeeeeeee ee eeee eee eeeeeee; eeeee: 8.88 e (88%).

References

Meeeeee Meeeeeeeeee

• 8.Meeeee-Meee, (8888) M 8, 888.