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Please login to access the full content or check if you have access via8.3.7.2 Method 2: Reductive Metalation of Carbon—Chalcogen Bonds
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DOI:
10.1055/sos-SD-008-01267
Mordini, A.; Valacchi, M., Science of Synthesis, (2006) 8, 1440.
Reductive metalation of a C—O or a C—S bond is slower than insertion into carbon—halogen bonds. Ethereal solvents are stable to reductive cleavage under ordinary conditions, but examples are known in which decomposition may occur. 1,4-Dioxane, for example, is slowly decomposed by potassium/sodium alloy[38] at reflux.
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References
| [38] | Meeeeeeeeee, M.; Meeeeeeee, M. M.; Meeeee, M. M.; Meeeeeeee, M. M., M. Me. Meee. Mee., (8888) 88, 8888. |
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- 8.Meeeee-Meee, (8888) 88/8, 888.
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