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10.4.1 Synthesis by Ring-Closure Reactions

DOI: 10.1055/sos-SD-010-00200

Rayner, C. M.; Graham, M. A.Science of Synthesis, (200110156.

The reaction of benzo[b]thiophenes with electrophiles almost invariably occurs with substitution in the thiophene ring. For this reason, derivatives with substituents in the benzene ring are often prepared by cyclization of appropriate precursors rather than electrophilic substitution reactions.


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