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10.7.1.1.1.5 Method 5: From 1,1-Diarylalkenes and Selenium Oxychloride

DOI: 10.1055/sos-SD-010-00348

Murphy, P. J.Science of Synthesis, (200110269.

Treatment of 1,1-diarylalkenes with selenium oxychloride leads to the formation of the benzo[b]selenopheno[2,3-b]benzo[b]selenophenes 8; however, the yields are generally poor (Scheme 6).[‌25‌] The reaction presumably proceeds via an additionelectrocyclizationelimination sequence for each ring system formed and is reported to be inhibited by the presence of electron-withdrawing groups on the aromatic rings.

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