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10.13.1.5.6.2 Method 2: Giving C-Carbon Indoles

DOI: 10.1055/sos-SD-010-00559

Joule, J. A.Science of Synthesis, (200110593.

The thermal rearrangement of allyl ethers of indole-2-esters is of preparative value; 4-allyl ethers[‌323‌,‌1208‌] give 5-allyl-1H-indol-4-ols, 5-ethers to 4-allyl-1H-indol-5-ols,[‌323‌,‌472‌,‌1209‌] 6-ethers to 7-allyl-1H-indol-6-ols,[‌323‌] and 7-ethers to 6-allyl-1H-indol-7-ols.[‌323‌]

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