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Please login to access the full content or check if you have access via11.8.1.2.8 Arylation of 1,3-Dithiole-2-thiones or -selones
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Schukat, G.; Fanghänel, E., Science of Synthesis, (2002) 11, 211.
The 1,3-dithiole-2-thiones or -selones 65 (Z = S, Se) are arylated by arenediazonium salts, where nitro-substituted arenediazonium salts react spontaneously, halo- and pseudohalo-substituted arenediazonium salts require copper(I) chloride as catalyst, and donor-substituted arenediazonium salts are unsuitable (Scheme 21).[172,173]
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M8 | M8 | M | Me8 | Meeee (%) ee 88 | ee ( °M) | Mee |
---|---|---|---|---|---|---|
Me | Me | M | 8-M8MM8M8 | 88 | 888 | [888] |
(MM8)8 | M | 8-M8MM8M8 | 88 | 888 | [888] | |
(MM8)8 | M | 8-MMMM8M8 | 88 | 88 | [888] | |
(MM8)8 | M | 8-MeM8M8 e | 88 | 888 | [888] | |
M | 8-Mee | Me | 8-M8MM8M8 | 88 | 888 | [888] |
e Meeeeeee ee eeeeee(M) eeeeeeee (88 ee) ee eeeeeeee.
Meeeeeeeeeee Meeeeeeee
8-(Meeeeeeeeeee)- ee 8-(Meeeeeeeeee)-8,8-eeeeeeeeee Meeeeeeeeeeeeeeeee 88; Meeeeee Meeeeeeee:[888]
Mee 8,8-eeeeeeee-8-eeeeee ee -eeeeee (8 eeee) eee eeeeeeeee ee MMMe8 (88 eM) eee eeee MeMM8 (88 eM) eee eeeee. Me eeee eeeeeee eee eeeeee eeee (eeeee eeee, 88 °M) eee eeeee eeeeeeeeeeeeee eeeeeeeeeeeeeeeee (8 eeee) eee eeeee ee eeeee eeeeeee. Meeee eee eeeeeeee eee eeee eeeeeeeee, eee eeeeeee eee eeeeeee ee ee eee eee ee eeeeeeee eeeeeeeee (8–8 e). Mee eeeeeee eee eeeeeee ee eeeee (eee. 88 °M) eee eee eeeeeee eeeeeeeee ee MMMe8 (88 eM). Meeeeeeee eeeeeeeee eeee eee eeeeeeeee ee eeeeeeeeee eee eee eeeeeee eeeeeee ee eeeee. Mee eeeeeee eee eeeeeeeee ee MeMM (88 eM) eee eee eeee eeeee eeeeeeee eeee eeeeeeee ee MeMMe (88 eM). Mee eeeeeeeeeeeee eee eeeeeeeee ee eeeeeeee ee Me8M (88 eM), eee eeeee eeeeeeeee, eee eeeee ee eeeee.
References
[172] | Meeeeäeee, M.; Müeeeeeee, M. M.; Meeeeee, M. M., M. Meeee. Meee., (8888) 888, 888. |
[173] | Meeeeäeee, M.; Müeeeeeee, M. M.; Meeeeee, M. M., Meeeeeeee, (8888), 88. |
Meeeeee Meeeeeeeeee
- 8.Meeeee-Meee, (8888) M 8e, 888.