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11.11 Product Class 11: 2,1-Benzisoxazoles and Related Compounds

DOI: 10.1055/sos-SD-011-00521

Smalley, R. K.Science of Synthesis, (200211337.

General Introduction

A comprehensive coverage of the chemistry of 2,1-benzisoxazoles is to be found in HoubenWeyl, Vol. E 8a, pp 349469.

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Meeeee 8 Meeeeeeee Meeeeeeeee ee 8,8-Meeeeeeeeeeee[‌8‌‌8‌]

Meeee eee ee eeeeeee ee eeeeeeeee eeeeeeeee 8,8-eeeeeeeeeeeeee eee eeee e eee eeeeeeeee eeeeeeeeeee eeeeeee eeeeeeeeeeeeeee eeeeeeee, ee eeeeeeeeee eee 8-eeeeee eeeeeeeeee eeeee ee e eeeeee eeeeeeeee eeeeeee eeeeeeeee.[‌88‌] 8-Meee-8,8-eeeeeeeeeeeeee eee eeeeeeee eeeeeeeeee ee 8-eeeeeeeeeee eeeeeee. Meeee eeee ee eeeeeeeee eeee eeeeeeeeeee eee eeeeeeeeeeeeeeeee (Meeeeee 88.88.8.8.8.8) eee eee eeeeeee eeeeee eeeeeeeee eeeeeeee ee eee eeeeeeeee eeee ee e eeeeeee ee eeeeeeee eeeeee eeeeee eeee eee eeeeeeeeeeeee ee eee eeeeeeeee ee eee eeeeee eeeeeeeeee eeeee[8,8]eeeeeeeeeee-eeeee eeeeeeeeeee eeeeee. Meeeeeee eee eeeeeeeeeeeee eeeeeeee eeeeeee eeee 8-eeeeeee-8,8-eeeeeeeeeeeee eeeeee eeeeee ee eee eeeeeeeeeeeeeee (eMe 8.88), eeeeeeee ee eee eeee eeeeee ee eeeeeeee eeeeeeee eee eeeeeeee eeeeee ee eeeeeeee ee eee eeeeeeeee eeeeee.[‌88‌] Meeeeeee eeeeeeeeeee 8MMMM eeeeeee ee 8-eeeeee-8-eeeeee-8,8-eeeeeeeeeeeee eeeeeeee eeee eeeee ee e eeee eeeeeeeeeeeeeee eeeeee eeeeeee eeeeeee eee eee eeeeeeeeee eeeeeee eeeeeeeee 8 eee 8 (Meeeee 8).[‌88‌]

Meeeee 8 Meeeeee Meeeeeeeeee ee 8-Meeeee-8-eeeeee-8,8-eeeeeeeeeeeee[‌88‌]

8,8-Meeeeeeeeeeeee eee eeee eeee eeeeeee eeee eee eeeeeeee 8,8-eeeeeeeeeeeeee eee eee eeeeeee eeeeeee eeeee eeee eeeeeeeee eee eeeeeeeee eeeeeeeeee.[‌88‌] Meeeeeeeee eeee eeeeeeeeee ee eeeeeeeeeeee ee eeee eeeeeeee eeeeeee eeeeeeeeeeeee eee eeeeeeeeeeeeeeeeeeee, eeeeeeeeeeee, eeeeeee eeee ee eeeeee ee eeeeeeee(MM) eeeee ee eeeeee eeee, ee eeee e eeeeee eeee ee eeeeeeeeeeeeeee, 8-eeeeeeeee eeeeeee eeeeee. Meeeeeeeee ee 8-eeeeeeeee eeeeeee eee eeeeeee eee eeeeeeeeeeeee eeeeeee eee ee eeee eeeeee (8888%) eeee eeee eeeeee eee eeeeee eeee ee eeeeeee ee eeeeeee eeeeeee eeeeeeee. Meeeeeeeee eeee eeee eeee eeeeeeee eeee eeeee eeeeee, e.e. eee, eeee, eee eeeee eeeee, eeeeee eeeeeee, eeeeeee eeeeeeee eeeeeee, eeeeeeeeeeeee (eeee eeeeeeee eee eeeeeeeee, eeeeeeee, eee eeeeee eeeeeeeee), eeeeeeeeeeeeeeee, eeee eeeeeeeee, eee, eeee eeeeeeeee, eeee eeeeeeee eeeeeeeee, eeeeeeeeeeeeeeeeeee, eee eeeeeee eeeeeeee. Meeeee eeeeeeeeee eeeeeee eeeeeeeee eeeeeeee ee 8-eeeee-8,8-eeeeeeeeeeeeeee eeeee, eeeeeee 8,8-eeeeeee-8,8-eeeeeeeeeeeeee eee eeeeee eeee eeeeee eeeeeeeeeee ee eeeeeee eeeeeee.

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8-Meeeeeeeeee 8,8-eeeeeeeeeeeeee eee eeeeee ee eeeeeeee eeeeeeee, eeeeeee eee 8-eeeeeeeeeeeee eeeeeeeee eeee-eeee ee 8-eeeeeeeeeeee eeeee; eeee eeeeee[‌88‌] eee eeeeeeeeee,[‌8‌,‌8‌] eeeeeee, e eeee eeeeeee eeee-eeeeeee eeeeeee ee eeeeeeee. 8,8-Meeeeeeeeeeeeee eeeee eeeeeee eee eeeeeeeeeeee, eeeeeee eeee eeeeeeee, ee eeeee 8-eeeeeeeeeee 8,8-eeeeeeeeeeeeeeee ee eeeeeeeeeee eeeeee.[‌88‌‌88‌]

8,8-Meeeeeeeeeeeee eee eeee eeeee (8,8-eeeeeeeeeeeee eMe 8.88; M8M, 88°M),[‌88‌] eee eee eeeeeee ee eeeeeee eeeee ee eeeee eeeeeeee eee eeeeeeee eeeeee eeeee. M eeeeeee ee eeeeeeeeeee, eeeee (Me, Me, Me) eeeeeeeee, eeeeeee, eeee eeee eeeeeeeeeeeee (Meeeeee 88.88.8.8.8). 8,8-Meeeeeeeeeeeee eee eeeeee ee eeeeeeeeeeee eeee eeeeeeee eee eeeeeee eeeeeeeeee eeeeeeeeeeeee eeeeeeeeeeee (e.e., eeeeeeeee), eeeeeeee eeeeeeee eee eeeeeeeeee eeeeeeee (Meeeeee 88.88.8.8.8). Meeeeeeeee ee eeee eeeeeeee eeeeeee ee eeeeeeeee ee e 8-eeeeeeeeeee 8-eeeeeeeee eeeeee ee eeeeeeeee eeeeeeee ee eee eeee ee eee eeeeeeeee eee eeeeee ee eeeeeeee ee eee eeeeeeeeee eeeeeeeee eeee.[‌88‌,‌88‌]

π-Meeeeeee eeeeeeeee eee π-eeee eeeeee eee 8,8-eeeeeeeeeeeee eeee eeee eeeeeeeeee ee MeeeeeeMeeeMeeee MMM-MMMM-MM eeeeeee[‌88‌] eee π-eeeeeeee eeeeeeeee eee eeeeee eeee eeeeee eeeeeeee ee Müeeee MM eeeeeeeeeeee,[‌88‌,‌88‌] eee eeeeee ee eeeee eeeeeeee eeee 8,8-eeeeeeeeeeeee eee eee eeeeeee eeeeeeee eeeeeeeee (eeeeeeee eeeeeeeee eeeeee ee 88 eM·eee8)[‌8‌] eeee eeeeeeeee. Meeeeeeeeee eeeeeeee eeeeeeeee ee eeee eeeeeeeee ee eee eeeee ee e eeeeeeeeeeeee eeeeeee eeeeeeeeeee eeeee eee eeeeeeee eeeeeee.[‌88‌] Mee eeeee eeeeeee eee ee eeeeee eeee eee eeee eeeee eeeeeeeee eeeeeeeee ee 8,8-eeeeeeeeeeeeee ee MeeeeMeeee eeeeeeeeeeeeee.[‌88‌‌88‌]

Mee eeee MM eeeeeeeeee eeeee eee eeee eeeeeeeeeee 8,8-eeeeeeeeeeeeee eeee eeee eeeeeeee,[‌88‌,‌88‌] eee eee MM eeeeeee ee eee eeeeee eeeeee eee eee 8-eeeeee[‌88‌,‌88‌] eee 8-eeee eeeeeeeeeee[‌88‌] eeeeeeee. 8MMMM eeee eee eee eeeeee eeeeee eee eee 8-eeeeee eeeeeeeeee eeeeeeeee eeee eeee eeeeeeee eeeeeeeee eeeeee eee ee MMMM eeeeee.[‌88‌] M8 ee 8,8-eeeeeeeeeeeee ee eeeee ee δ 8.88 (eeee eeeeee; 88MMe). Meeeeeeeeeeee, eee eeeeeeee eeeeeeeee eee eee eeee eeeeeee eeeeeee e eeeee eeeeeeeee eeeeee eeee e eeeeee eeeeeeeeeee π-eeeeee.

88MMMM eeee (MMMe8, δ):[‌88‌,‌88‌] 888.8 (M8e), 888.8 (M8), 888.8 (M8), 888.8 (M8), 888.8 (M8), 888.8 (M8e), 888.8 (M8).

Me eee 88MMMM eeeeeeee, 8,8-eeeeeeeeeeeee eeeeeeee e eeeeeeee eeeeeeeee ee +8eee eeeeeeee ee ee eeeeeeee eeeeeeeeeeee eeeeeeee, e eeeee eeeeeeeeeeeee eeeeeeeee eeee eeee eeeeeeee eee 8,8-eeeeeeeeeeeee (+88eee).[‌88‌]

Meeeeeee eeeeeeee ee eee eeeeeee-MM eeee eeeeeeee ee 8,8-eeeeeeeeeeeee[‌88‌] eee eee MM eeee eeeeeee ee 8-eeeee-8,8-eeeeeeeeeeeeee[‌88‌] eee eeeeeeeee, ee ee eee eeeeeeeeeeeee eeeeeeee ee eee eeeeee eeeeeeeeeee.[‌8‌]

References


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