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Please login to access the full content or check if you have access via11.18.1.1.1.4.5 Variation 5: With Benzoylsulfanylcopper
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Ulrich, H., Science of Synthesis, (2002) 11, 859.
2-Arylbenzothiazoles are obtained in 43–96% yield in the reaction of 2-iodoaniline derivatives with benzoylsulfanylcopper in hexamethylphosphoric triamide.[134] For example, reaction of 2-iodoaniline (88, R1 = H) with benzoylsulfanylcopper affords 2-phenylbenzothiazole (89, R1 = H; R2 = Ph) in 85% yield (Scheme 35).
Meeeee 88 Meeeeeeeeee ee 8-Meeeeeeeeeee eeee Meeeeeeeeeeeeeeeeeeee[888]
Meeeeeeeeeee Meeeeeeee
8-Meeeeeeeeeeeeeeeeee (88, M8 = M; M8 = Me):[888]
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M eeeeeee ee 8-eeeeeeeeeee (888 ee, 8 eeee) eee eeeeeeeeeeeeeeeeeeeee (888 ee, 8 eeee) ee MMMM (8 eM) eee eeeeee eeeee M8 eee 8 e ee 888–888°M. Meeee eeeeeee eee eeeeeee eee eeeeee eeee eeeee (888 eM). Meeee eeeeee eeeeeeeee eeeeeeeeeeee, eeeee eeee eeeeeeee, eeeeee (M8M, 888 eM), eee eeeee. Meeeeeeeee eeee eeeeee (888 eM) ee e Meeeeee eeeeeeeee, eeeeeee ee eee eeeeeee, eee eeeeeeeeeeeeeee (MeMM) eeee eee eeeeeee; eeeee: 888 ee (88%); ee 888–888°M.
References
| [134] | Meeee, M.; Mee, M.; Meeeeeee, M.; Meeeee, M., Meeeeeeee, (8888), 888. |
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- 8.Meeeee-Meee, (8888) M 8e, 888.
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