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DOI:
10.1055/sos-SD-012-00398
Grimmett, M. R., Science of Synthesis, (2002) 12, 347.
In these procedures, the 1—5 and 3—4 bonds are formed. The most common synthetic methods of this type utilize amidines, guanidines, ureas, and thioureas as the N—C—N fragment reacting with a suitably functionalized carbonyl compound acting as the C—C synthon (Scheme 26).
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