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13.30.4.1.4.2 Of Other Functions

DOI: 10.1055/sos-SD-013-01452

Brigas, A. F.Science of Synthesis, (200413903.

Standard modifications of substituents can be applied to tetrazoles. In general, substituents attached to a tetrazole, such as amines, behave normally and the electronic effects of the tetrazole are those of a strong electron-withdrawing group. Such transformations include the Sandmeyer reaction,[‌237‌] leading to the conversion of amino into nitro substituents, reaction with Lawesson's reagent for the conversion of oxygen into sulfur in high yields;[‌216‌] and the synthesis of imines from amines and carbonyls.[‌238‌]

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